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HomeProduct name list1,2,3,6-TETRAHYDROPYRIDINE

1,2,3,6-TETRAHYDROPYRIDINE

  • CAS NO.:694-05-3
  • Empirical Formula: C5H9N
  • Molecular Weight: 83.13
  • MDL number: MFCD00005949
  • EINECS: 211-766-2
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-05-25 10:25:51
1,2,3,6-TETRAHYDROPYRIDINE Structural

What is 1,2,3,6-TETRAHYDROPYRIDINE?

Chemical properties

Clear colorless to pale yellow liquid

The Uses of 1,2,3,6-TETRAHYDROPYRIDINE

Organic intermediate.

The Uses of 1,2,3,6-TETRAHYDROPYRIDINE

Used to form ene-endo-spirocyclic ammonium ylids for [2,3]-sigmatropic rearrangement to pyrroloazepinones and oxazepinones.

What are the applications of Application

1,2,3,6-Tetrahydropyridine is used to form ene-endo-spirocyclic ammonium ylids

Definition

ChEBI: 3-piperideine is a piperideine.

General Description

A colorless liquid. Density 0.913 g / cm3 and insoluble in water. Hence floats on water. Flash point near 110°F. Vapors heavier than air. Used to make other chemicals.

Air & Water Reactions

Flammable. Insoluble in water.

Reactivity Profile

1,2,3,6-TETRAHYDROPYRIDINE neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Health Hazard

May cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Properties of 1,2,3,6-TETRAHYDROPYRIDINE

Melting point: −48 °C(lit.)
Boiling point: 108 °C(lit.)
Density  0.911 g/mL at 25 °C(lit.)
refractive index  n20/D 1.48(lit.)
Flash point: 61 °F
solubility  Chloroform (Slightly), Methanol (Slightly)
pka 10.22±0.10(Predicted)
form  Powder
color  White to pale yellow-cream
Stability: Light Sensitive
CAS DataBase Reference 694-05-3(CAS DataBase Reference)
EPA Substance Registry System Pyridine, 1,2,3,6-tetrahydro- (694-05-3)

Safety information for 1,2,3,6-TETRAHYDROPYRIDINE

Signal word Danger
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H225:Flammable liquids
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for 1,2,3,6-TETRAHYDROPYRIDINE

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