1,1,1-TRIMETHYLHYDRAZINIUM IODIDE
- CAS NO.:3288-80-0
- Empirical Formula: C3H11IN2
- Molecular Weight: 202.04
- MDL number: MFCD00464984
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-12-18 14:07:02
What is 1,1,1-TRIMETHYLHYDRAZINIUM IODIDE?
The Uses of 1,1,1-TRIMETHYLHYDRAZINIUM IODIDE
1,1,1-Trimethylhydrazinium iodide (TMHI) may be employed for the amination of 1-X-3,5-dinitrobenzenes.
What are the applications of Application
1,1,1-Trimethylhydrazinium iodide is a useful reagent for aromatic amination
General Description
1,1,1-Trimethylhydrazinium iodide ([(CH3)3N-NH2]I, TMHI) is widely employed as a vicarious nucleophilic substitution (VNS) reagent for various aromatic amination reactions. On reaction with silver salt, it affords the following salts: nitrate (([(CH3)3N-NH2][NO3]), perchlorate ([(CH3)3N-NH2][ClO4]), azide ([(CH3)3N-NH2][N3]), 5-amino-1H-tetrazolate ([(CH3)3N-NH2][H2N-CN4]) and sulfate ([(CH3)3N-NH2]2[SO4].2H2O).
Properties of 1,1,1-TRIMETHYLHYDRAZINIUM IODIDE
Melting point: | 225-230 °C (dec.) (lit.) |
EPA Substance Registry System | 1,1,1-trimethylhydrazinium iodide (3288-80-0) |
Safety information for 1,1,1-TRIMETHYLHYDRAZINIUM IODIDE
Signal word | Danger |
Pictogram(s) |
Exclamation Mark Irritant GHS07 Health Hazard GHS08 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation H360:Reproductive toxicity |
Precautionary Statement Codes |
P201:Obtain special instructions before use. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P308+P313:IF exposed or concerned: Get medical advice/attention. |
Computed Descriptors for 1,1,1-TRIMETHYLHYDRAZINIUM IODIDE
New Products
Tert-butyl bis(2-chloroethyl)carbamate 4-Methylphenylacetic acid N-Boc-D-alaninol N-BOC-D/L-ALANINOL N-octanoyl benzotriazole 3-Morpholino-1-(4-nitrophenyl)-5,6-dihydropyridin- 2(1H)-one Furan-2,5-Dicarboxylic Acid DIETHYL AMINOMALONATE HYDROCHLORIDE 1,1’-CARBONYLDIIMIDAZOLE R-2-BENZYLOXY PROPIONIC ACID 1,1’-CARBONYLDI (1,2-4 TRIAZOLE) N-METHYL INDAZOLE-3-CARBOXYLIC ACID (2-Hydroxyphenyl)acetonitrile 4-Bromopyrazole 5-BROMO-2CYANO PYRIDINE 5,6-Dimethoxyindanone 5-broMo-2-chloro-N-cyclopentylpyriMidin-4-aMine 2-(Cyanocyclohexyl)acetic acid 4-methoxy-3,5-dinitropyridine 1-(4-(aminomethyl)benzyl)urea hydrochloride 2-aminopropyl benzoate hydrochloride diethyl 2-(2-((tertbutoxycarbonyl)amino) ethyl)malonate tert-butyl 4- (ureidomethyl)benzylcarbamate Ethyl-2-chloro((4-methoxyphenyl)hydrazono)acetateRelated products of tetrahydrofuran
1,1,1-TRIMETHYLHYDRAZINIUM IODIDE
2-Hydroxy-3-methoxybenzaldehyde, hyrazone with 1,1,1-trimethylhydrazon ium iodide
(2S)-1-METHYL-1-[N-(DIPHENYLMETHYLENE)]-2-HYDROXYMETHYLPYRROLIDINE, HYDRAZONIUM IODIDE
2-[(DIMETHYLAMINO)METHYLENE]-1,1,1-TRIMETHYLHYDRAZINIUM IODIDE
N-(1-METHYLPYRROLIDIN-1-IUM)-2-[(4,6-DIMETHOXYPYRIMIDIN-2-YL)OXY]BENZAMIDE, IODIDE
SALOR-INT L166707-1EA
1,1,1-TRIMETHYLHYDRAZINIUM IODIDE, TECH
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