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HomeProduct name list1,1,1-TRIMETHYLHYDRAZINIUM IODIDE

1,1,1-TRIMETHYLHYDRAZINIUM IODIDE

1,1,1-TRIMETHYLHYDRAZINIUM IODIDE Structural

What is 1,1,1-TRIMETHYLHYDRAZINIUM IODIDE?

The Uses of 1,1,1-TRIMETHYLHYDRAZINIUM IODIDE

1,1,1-Trimethylhydrazinium iodide (TMHI) may be employed for the amination of 1-X-3,5-dinitrobenzenes.

What are the applications of Application

1,1,1-Trimethylhydrazinium iodide is a useful reagent for aromatic amination

General Description

1,1,1-Trimethylhydrazinium iodide ([(CH3)3N-NH2]I, TMHI) is widely employed as a vicarious nucleophilic substitution (VNS) reagent for various aromatic amination reactions. On reaction with silver salt, it affords the following salts: nitrate (([(CH3)3N-NH2][NO3]), perchlorate ([(CH3)3N-NH2][ClO4]), azide ([(CH3)3N-NH2][N3]), 5-amino-1H-tetrazolate ([(CH3)3N-NH2][H2N-CN4]) and sulfate ([(CH3)3N-NH2]2[SO4].2H2O).

Properties of 1,1,1-TRIMETHYLHYDRAZINIUM IODIDE

Melting point: 225-230 °C (dec.) (lit.)
EPA Substance Registry System 1,1,1-trimethylhydrazinium iodide (3288-80-0)

Safety information for 1,1,1-TRIMETHYLHYDRAZINIUM IODIDE

Signal word Danger
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
ghs
Health Hazard
GHS08
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
H360:Reproductive toxicity
Precautionary Statement Codes P201:Obtain special instructions before use.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313:IF exposed or concerned: Get medical advice/attention.

Computed Descriptors for 1,1,1-TRIMETHYLHYDRAZINIUM IODIDE

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