1,1'-Bis(diisopropylphosphino)ferrocene
- CAS NO.：97239-80-0
- Empirical Formula: C22H36FeP210*
- Molecular Weight: 418.31
- MDL number: MFCD02684559
- EINECS: 677-500-6
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-10-14 18:20:50
What is 1,1'-Bis(diisopropylphosphino)ferrocene?
Chemical properties
orange crystalline powder
The Uses of 1,1'-Bis(diisopropylphosphino)ferrocene
The general and efficient cross-coupling of thiols with aryl halides was developed utilizing Pd(OAc) 2 /1,1?-bis(diisopropylphosphino)ferrocene as the catalyst. The oxidative electrochemistry of dippf was examined, and it was found to follow an ECDim mechanism. Seven new compounds containing dippf were prepared and characterized spectroscopically. The crystal structures of [MCl2(dippf)] (M = Pt and Zn) were determined.
Properties of 1,1'-Bis(diisopropylphosphino)ferrocene
| Melting point: | 50-52 °C(lit.) |
| Flash point: | >230 °F |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| form | Powder |
| color | orange-yellow |
| Water Solubility | Insoluble in water. |
| CAS DataBase Reference | 97239-80-0(CAS DataBase Reference) |
Safety information for 1,1'-Bis(diisopropylphosphino)ferrocene
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. |
Computed Descriptors for 1,1'-Bis(diisopropylphosphino)ferrocene
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