1-PHENYL-1-TRIMETHYLSILOXYETHYLENE
Synonym(s):α-(Trimethylsiloxy)styrene;Acetophenone enol trimethylsilyl ether
- CAS NO.：13735-81-4
- Empirical Formula: C11H16OSi
- Molecular Weight: 192.33
- MDL number: MFCD00008582
- EINECS: 237-308-1
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-12-18 14:15:30
What is 1-PHENYL-1-TRIMETHYLSILOXYETHYLENE?
The Uses of 1-PHENYL-1-TRIMETHYLSILOXYETHYLENE
1-Phenyl-1-trimethylsiloxyethylene has been used in the synthesis of β-amino ketones in water via Mannich-type reaction and cis-2,6-disubstituted dihydropyrans via three-component, one-pot cascade reaction. It is also used as chemical additives and intermediates.
The Uses of 1-PHENYL-1-TRIMETHYLSILOXYETHYLENE
1-Phenyl-1-trimethylsiloxyethylene has been used in the synthesis of:
- β-amino ketones in water via Mannich-type reaction
- cis-2,6-disubstituted dihydropyrans via three-component, one-pot cascade reaction
General Description
1-Phenyl-1-trimethylsiloxyethylene is a styrene type silyl enol ether, reacts with formaldehyde and 2,4-pentanedione to yield the corresponding dihydropyran. It also undergoes Mukaiyama aldol reaction with aldehydes in water in the presence of amphiphilic calix[6]arene derivatives as surfactants.
Properties of 1-PHENYL-1-TRIMETHYLSILOXYETHYLENE
| Melting point: | 122-123 °C |
| Boiling point: | 88-89 °C/11 mmHg (lit.) |
| Density | 0.938 g/mL at 25 °C (lit.) |
| vapor density | >1 (vs air) |
| refractive index | n |
| Flash point: | 174 °F |
| storage temp. | 2-8°C |
| form | clear liquid |
| color | Colorless to Light orange to Yellow |
| Specific Gravity | 0.938 |
| Water Solubility | Reacts with water. |
| Sensitive | Moisture Sensitive |
| Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
| BRN | 1306914 |
| CAS DataBase Reference | 13735-81-4(CAS DataBase Reference) |
| EPA Substance Registry System | Silane, trimethyl[(1-phenylethenyl)oxy]- (13735-81-4) |
Safety information for 1-PHENYL-1-TRIMETHYLSILOXYETHYLENE
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 1-PHENYL-1-TRIMETHYLSILOXYETHYLENE
New Products
Tert-butyl bis(2-chloroethyl)carbamate (S)-3-Aminobutanenitrile hydrochloride N-Boc-D-alaninol N-BOC-D/L-ALANINOL N-octanoyl benzotriazole 4-Hydrazinobenzoic acid 3,4-Dibenzyloxybenzaldehyde Electrolytic Iron Powder 1,1’-CARBONYLDIIMIDAZOLE R-2-BENZYLOXY PROPIONIC ACID 4-HYDROXY BENZYL ALCOHOL 1,1’-CARBONYLDI (1,2-4 TRIAZOLE) S-2-CHLORO PROPIONIC ACID (2-Hydroxyphenyl)acetonitrile 4-Bromopyrazole 5-BROMO-2CYANO PYRIDINE 5,6-Dimethoxyindanone 5-broMo-2-chloro-N-cyclopentylpyriMidin-4-aMine 3-(Hydroxymethyl)benzoate N-Boc-2-chloroethylamine 1-Bromo-2-methoxy-3-nitrobenzene N-Methyl-3-cyclopenten-1-amine 2-Bromo-3-hydroxybenzaldehyde 1H-indazole-5-carboxamideRelated products of tetrahydrofuran
You may like
-
1-Phenyl-1-trimethylsiloxyethylene CAS 13735-81-4View Details
13735-81-4 -
1-Phenyl-1-trimethylsilyloxyethylene CAS 13735-81-4View Details
13735-81-4 -
1-Phenyl-1-trimethylsiloxyethylene CAS 13735-81-4View Details
13735-81-4 -
7441-43-2 98%View Details
7441-43-2 -
1260741-78-3 6-Bromo-3-iodo-1-methyl-1H-indazole 98%View Details
1260741-78-3 -
4-bromo-3,5-dimethylbenzenesulfonyl chloride 1581266-79-6 98%View Details
1581266-79-6 -
2490430-37-8 98%View Details
2490430-37-8 -
N-(5-Amino-2-methylphenyl)acetamide 5434-30-0 98%View Details
5434-30-0
Statement: All products displayed on this website are only used for non medical purposes such as industrial applications or scientific research, and cannot be used for clinical diagnosis or treatment of humans or animals. They are not medicinal or edible.