1-METHYL-4-(METHYLSULFINYL)BENZENE
- CAS NO.:934-72-5
- Empirical Formula: C8H10OS
- Molecular Weight: 154.23
- MDL number: MFCD00075175
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-06-08 17:06:38
What is 1-METHYL-4-(METHYLSULFINYL)BENZENE?
The Uses of 1-METHYL-4-(METHYLSULFINYL)BENZENE
Methyl p-tolyl sulfoxide may be used as a catalyst in the preparation of homoallylic alcohols by the allylation of aldehydes with allyltrichlorosilane. It may be used as a ligand in the synthesis of molybdenum chlorocomplexes.
Synthesis Reference(s)
Chemistry Letters, 15, p. 967, 1986
Synthetic Communications, 19, p. 1569, 1989 DOI: 10.1080/00397918908051052
Tetrahedron Letters, 19, p. 3415, 1978
General Description
Methyl p-tolyl sulfoxide (MTSO), an alkyl-substituted p-tolyl sulfoxide, is a Lewis base. It behaves as an activator of silicon tetrachloride that is employed in aza-Diels-Alder reaction.
Properties of 1-METHYL-4-(METHYLSULFINYL)BENZENE
Melting point: | 44-46 °C (lit.) |
Boiling point: | 113-114 °C/2 mmHg (lit.) |
Density | 1.1125 (rough estimate) |
refractive index | 1.5780 (estimate) |
Flash point: | >230 °F |
solubility | soluble in Methanol |
form | powder to crystal |
color | White to Almost white |
Safety information for 1-METHYL-4-(METHYLSULFINYL)BENZENE
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. |
Computed Descriptors for 1-METHYL-4-(METHYLSULFINYL)BENZENE
New Products
Tert-butyl bis(2-chloroethyl)carbamate 4-Methylphenylacetic acid N-Boc-D-alaninol N-BOC-D/L-ALANINOL N-octanoyl benzotriazole 3-Morpholino-1-(4-nitrophenyl)-5,6-dihydropyridin- 2(1H)-one Furan-2,5-Dicarboxylic Acid DIETHYL AMINOMALONATE HYDROCHLORIDE 1,1’-CARBONYLDIIMIDAZOLE R-2-BENZYLOXY PROPIONIC ACID 1,1’-CARBONYLDI (1,2-4 TRIAZOLE) N-METHYL INDAZOLE-3-CARBOXYLIC ACID (2-Hydroxyphenyl)acetonitrile 4-Bromopyrazole 5-BROMO-2CYANO PYRIDINE 5,6-Dimethoxyindanone 5-broMo-2-chloro-N-cyclopentylpyriMidin-4-aMine 2-(Cyanocyclohexyl)acetic acid 4-methoxy-3,5-dinitropyridine 1-(4-(aminomethyl)benzyl)urea hydrochloride 2-aminopropyl benzoate hydrochloride diethyl 2-(2-((tertbutoxycarbonyl)amino) ethyl)malonate tert-butyl 4- (ureidomethyl)benzylcarbamate Ethyl-2-chloro((4-methoxyphenyl)hydrazono)acetateRelated products of tetrahydrofuran
4,4'-Dimethyldiphenylsulfoxide
N-AMINO-2-((4-METHYLPHENYL)SULFONYL)ETHANAMIDE
2-((4-METHYLPHENYL)SULFONYL)ETHANAMIDE
4-TOLUENESULFONYLACETIC ACID
2-(P-TOLUENESULFONYL)ACETOPHENONE
PHENYL P-TOLYL SULFONE
4'-METHYL-2(P-TOLYL SULFONYL)ACETOPHENONE
Tosylmethyl isocyanide
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