1-Methoxy-2,4-dinitrobenzene
- CAS NO.：119-27-7
- Empirical Formula: C7H6N2O5
- Molecular Weight: 198.13
- MDL number: MFCD00035745
- EINECS: 204-310-9
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-12-18 14:15:30
What is 1-Methoxy-2,4-dinitrobenzene?
Chemical properties
yellow crystals or crystalline powder
The Uses of 1-Methoxy-2,4-dinitrobenzene
It can be used as a dye ingredient. It is one of the insensitive nitroaromatic ingredients increasingly used as a replacement for 2,4,6-trinitrotoluene (TNT) in munitions.
Definition
ChEBI: A member of the class of dinitroanisoles that is 2-nitroanisole in which the hydrogen para to the methoxy group is replaced by a second nitro group.
Production Methods
2,4-Dinitrochlorobenzene is treated with methanolic sodium hydroxide in a process similar to that described for 4-nitroanisole. 2,4-Dinitrophenetole [610-54-8] is similarly manufactured by using ethanol.
Flammability and Explosibility
Not classified
Safety Profile
Poison by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also NITRO COMPOUNDS of AROMATIC HYDROCARBONS and NITRATES.
Purification Methods
Purify the anisole by repeated crystallisation from EtOH, MeOH or H2O and dry it in a vacuum desiccator over P2O5. The naphthalene complex has m 69o (from EtOH). [Beilstein 6 III 869, 6 IV 1385.
Properties of 1-Methoxy-2,4-dinitrobenzene
| Melting point: | 94-96 °C(lit.) |
| Boiling point: | 207°C/12mm |
| Density | 1.34 g/mL at 25 °C(lit.) |
| vapor pressure | 0.001Pa at 25℃ |
| refractive index | 1.5460 (estimate) |
| Flash point: | 207°C/12mm |
| Water Solubility | Solubility in hot methanol; almost transparency. Water solubility, 155 mg/L 15°C. Completely soluble in ethyl acetate & acetone. |
| BRN | 1881474 |
| CAS DataBase Reference | 119-27-7(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzene, 1-methoxy-2,4-dinitro-(119-27-7) |
| EPA Substance Registry System | 2,4-Dinitroanisole (119-27-7) |
Safety information for 1-Methoxy-2,4-dinitrobenzene
| Pictogram(s) |
 Skull and Crossbones Acute Toxicity GHS06 |
| GHS Hazard Statements |
H301:Acute toxicity,oral |
| Precautionary Statement Codes |
P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P270:Do not eat, drink or smoke when using this product. P321:Specific treatment (see … on this label). P405:Store locked up. |
Computed Descriptors for 1-Methoxy-2,4-dinitrobenzene
New Products
(S)-3-Aminobutanenitrile hydrochloride 4-Methylphenylacetic acid N-Boc-D-alaninol N-BOC-D/L-ALANINOL Tert-butyl bis(2-chloroethyl)carbamate 3-Morpholino-1-(4-nitrophenyl)-5,6-dihydropyridin- 2(1H)-one Furan-2,5-Dicarboxylic Acid Tropic acid 1-Bromo-3,5-Di-Tert-Butylbenzene S-2-CHLORO PROPIONIC ACID ETHYL ISOCYANOACETATE 2-Bromo-1,3-Bis(Dimethylamino)Trimethinium Hexafluorophosphate 4-IODO BENZOIC ACID 3-NITRO-2-METHYL ANILINE 1-(2,4-DICHLOROPHENYL) ETHANAMINE (2-Hydroxyphenyl)acetonitrile 4-Bromopyrazole 2-(Cyanocyclohexyl)acetic acid 4-methoxy-3,5-dinitropyridine 1-(4-(aminomethyl)benzyl)urea hydrochloride 2-aminopropyl benzoate hydrochloride diethyl 2-(2-((tertbutoxycarbonyl)amino) ethyl)malonate tert-butyl 4- (ureidomethyl)benzylcarbamate Ethyl-2-chloro((4-methoxyphenyl)hydrazono)acetateRelated products of tetrahydrofuran
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