1-Methoxy-2,4-dinitrobenzene

CAS NO.：119-27-7
Empirical Formula: C7H6N2O5
Molecular Weight: 198.13
MDL number: MFCD00035745
EINECS: 204-310-9
SAFETY DATA SHEET (SDS)
Update Date: 2023-10-21 11:18:04

What is 1-Methoxy-2,4-dinitrobenzene?

Chemical properties

yellow crystals or crystalline powder

The Uses of 1-Methoxy-2,4-dinitrobenzene

It can be used as a dye ingredient. It is one of the insensitive nitroaromatic ingredients increasingly used as a replacement for 2,4,6-trinitrotoluene (TNT) in munitions.

Definition

ChEBI: A member of the class of dinitroanisoles that is 2-nitroanisole in which the hydrogen para to the methoxy group is replaced by a second nitro group.

Production Methods

2,4-Dinitrochlorobenzene is treated with methanolic sodium hydroxide in a process similar to that described for 4-nitroanisole. 2,4-Dinitrophenetole [610-54-8] is similarly manufactured by using ethanol.

Flammability and Explosibility

Not classified

Safety Profile

Poison by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also NITRO COMPOUNDS of AROMATIC HYDROCARBONS and NITRATES.

Purification Methods

Purify the anisole by repeated crystallisation from EtOH, MeOH or H2O and dry it in a vacuum desiccator over P2O5. The naphthalene complex has m 69o (from EtOH). [Beilstein 6 III 869, 6 IV 1385.

Properties of 1-Methoxy-2,4-dinitrobenzene

Melting point:	94-96 °C(lit.)
Boiling point:	207°C/12mm
Density	1.34 g/mL at 25 °C(lit.)
vapor pressure	0.001Pa at 25℃
refractive index	1.5460 (estimate)
Flash point:	207°C/12mm
Water Solubility	Solubility in hot methanol; almost transparency. Water solubility, 155 mg/L 15°C. Completely soluble in ethyl acetate & acetone.
BRN	1881474
CAS DataBase Reference	119-27-7(CAS DataBase Reference)
NIST Chemistry Reference	Benzene, 1-methoxy-2,4-dinitro-(119-27-7)
EPA Substance Registry System	2,4-Dinitroanisole (119-27-7)

Safety information for 1-Methoxy-2,4-dinitrobenzene

Pictogram(s)	Skull and Crossbones Acute Toxicity GHS06
GHS Hazard Statements	H301:Acute toxicity,oral
Precautionary Statement Codes	P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P270:Do not eat, drink or smoke when using this product. P321:Specific treatment (see … on this label). P405:Store locked up.