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HomeProduct name list1-Hydroxy-2,1-benzoxaborolane

1-Hydroxy-2,1-benzoxaborolane

Synonym(s):1,3-Dihydro-1-hydroxy-2,1-benzoxaborole;2-(Hydroxymethyl)phenylboronic acid hemiester

1-Hydroxy-2,1-benzoxaborolane Structural

What is 1-Hydroxy-2,1-benzoxaborolane?

Chemical properties

Solid

The Uses of 1-Hydroxy-2,1-benzoxaborolane

Oxaboroles and benzoxaboroles are useful substrates to prepare allylic and benzylic alcohols via Suzuki coupling.

What are the applications of Application

2-(Hydroxymethyl)phenylboronic acid cyclic monoester is a useful substrate in the preparation of allylic and benzylic alcohols vial Suzuki coupling

Definition

ChEBI: 1-hydroxy-2,1-benzoxaborole is a member of the class of benzoxaboroles that is 2,1-benzoxaborole in which the hydrogen attached to the boron atom is replaced by a hydroxy group.

Synthesis Reference(s)

Journal of the American Chemical Society, 80, p. 835, 1958 DOI: 10.1021/ja01537a021

Properties of 1-Hydroxy-2,1-benzoxaborolane

Melting point: 95-100 °C
Boiling point: 237.2±43.0 °C(Predicted)
Density  1.18±0.1 g/cm3(Predicted)
storage temp.  Inert atmosphere,2-8°C
form  powder to crystal
pka 7.01±0.20(Predicted)
color  White to Almost white
BRN  4333
CAS DataBase Reference 5735-41-1(CAS DataBase Reference)

Safety information for 1-Hydroxy-2,1-benzoxaborolane

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405:Store locked up.

Computed Descriptors for 1-Hydroxy-2,1-benzoxaborolane

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