1-Bromotridecane
Synonym(s):Tridecyl bromide
- CAS NO.：765-09-3
- Empirical Formula: C13H27Br
- Molecular Weight: 263.26
- MDL number: MFCD00000227
- EINECS: 212-138-0
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-12-18 14:08:52
What is 1-Bromotridecane?
Chemical properties
light yellow liquid
The Uses of 1-Bromotridecane
1-Bromotridecane is a long chain alkyl bromide with skin sensitization potency. 1-Bromotridecane may potentially enhance plant stimulator activity.
Preparation
1-Bromotridecane is prepared from 1-tridecanol.
What are the applications of Application
1-Bromotridecane was used in the synthesis of:
tetradecanoic acid enriched with 13C at carbons 1, 3, or 6
(Z)-7-henicosene
Pentadecanal
(Z)-(2′R)-[N-carboethoxypyrrolidine]tetradec-1-ene
2,3,6,7,10,11,14,15-octaalkyloxytetrabenzo[a,d,g,jlcyclododecatetraenes (CTTV-n) containing n=4-15 methylenic units in the alkyloxy substituents
Coupling reaction between the dilithio-derivative of propargyl alcohol with 1-bromotridecane in liquid ammonia gave 2-hexadecyne-1-ol.
Synthesis Reference(s)
The Journal of Organic Chemistry, 44, p. 3405, 1979 DOI: 10.1021/jo01333a029
Properties of 1-Bromotridecane
| Melting point: | 4-7 °C (lit.) |
| Boiling point: | 148-150 °C/10 mmHg (lit.) |
| Density | 1.03 g/mL at 25 °C (lit.) |
| vapor density | 9.2 (vs air) |
| refractive index | n |
| Flash point: | >230 °F |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| solubility | Chloroform, Methanol |
| form | Oil |
| color | Colourless |
| BRN | 1739992 |
| Stability: | Stable. Incompatible with strong bases, strong oxidizing agents. |
| CAS DataBase Reference | 765-09-3(CAS DataBase Reference) |
| NIST Chemistry Reference | Tridecane, 1-bromo-(765-09-3) |
| EPA Substance Registry System | Tridecane, 1-bromo- (765-09-3) |
Safety information for 1-Bromotridecane
| Signal word | Danger |
| Pictogram(s) |
 Corrosion Corrosives GHS05  Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H302:Acute toxicity,oral H315:Skin corrosion/irritation H318:Serious eye damage/eye irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P280:Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 1-Bromotridecane
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