1-Bromotridecane

Synonym(s):Tridecyl bromide

CAS NO.：765-09-3
Empirical Formula: C13H27Br
Molecular Weight: 263.26
MDL number: MFCD00000227
EINECS: 212-138-0
SAFETY DATA SHEET (SDS)
Update Date: 2024-10-30 18:52:02

What is 1-Bromotridecane?

Chemical properties

light yellow liquid

The Uses of 1-Bromotridecane

1-Bromotridecane is a long chain alkyl bromide with skin sensitization potency. 1-Bromotridecane may potentially enhance plant stimulator activity.

Preparation

1-Bromotridecane is prepared from 1-tridecanol.
synthesis of 1-Bromotridecane

What are the applications of Application

1-Bromotridecane was used in the synthesis of:
tetradecanoic acid enriched with 13C at carbons 1, 3, or 6
(Z)-7-henicosene
Pentadecanal
(Z)-(2′R)-[N-carboethoxypyrrolidine]tetradec-1-ene
2,3,6,7,10,11,14,15-octaalkyloxytetrabenzo[a,d,g,jlcyclododecatetraenes (CTTV-n) containing n=4-15 methylenic units in the alkyloxy substituents
Coupling reaction between the dilithio-derivative of propargyl alcohol with 1-bromotridecane in liquid ammonia gave 2-hexadecyne-1-ol.

Synthesis Reference(s)

The Journal of Organic Chemistry, 44, p. 3405, 1979 DOI: 10.1021/jo01333a029

Properties of 1-Bromotridecane

Melting point:	4-7 °C (lit.)
Boiling point:	148-150 °C/10 mmHg (lit.)
Density	1.03 g/mL at 25 °C (lit.)
vapor density	9.2 (vs air)
refractive index	n20/D 1.459(lit.)
Flash point:	>230 °F
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
solubility	Chloroform, Methanol
form	Oil
color	Colourless
BRN	1739992
Stability:	Stable. Incompatible with strong bases, strong oxidizing agents.
CAS DataBase Reference	765-09-3(CAS DataBase Reference)
NIST Chemistry Reference	Tridecane, 1-bromo-(765-09-3)
EPA Substance Registry System	Tridecane, 1-bromo- (765-09-3)

Safety information for 1-Bromotridecane

Signal word	Danger
Pictogram(s)	Corrosion Corrosives GHS05 Exclamation Mark Irritant GHS07
GHS Hazard Statements	H302:Acute toxicity,oral H315:Skin corrosion/irritation H318:Serious eye damage/eye irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes	P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P280:Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.