(+)-B-METHOXYDIISOPINOCAMPHEYLBORANE
Synonym(s):(−)-Diisopinocampheylmethoxyborane;(+)-Diisopinocampheylmethoxyborane
- CAS NO.：85134-98-1
- Empirical Formula: C21H37BO
- Molecular Weight: 316.33
- MDL number: MFCD00074809
- SAFETY DATA SHEET (SDS)
- Update Date: 2022-11-11 11:01:00
What is (+)-B-METHOXYDIISOPINOCAMPHEYLBORANE?
The Uses of (+)-B-METHOXYDIISOPINOCAMPHEYLBORANE
Reactant involved in organic synthesis reactions such as:
- Double allylboration for synthesis of fragments of tetrafibricin
- Anticancer cytotoxic monorhizopodin synthesis
- Annulation of cyclic allylsilanes
- Asymmetric synthesis of β-amino-α-hydroxy acid taxol side chain analogs
General Description
B-Methoxydiisopinocampheylborane (Ipc2BOMe) is an organoborane compound, which is prepared from excess α-pinene, borane dimethylsulfide, and methanol via the formation of an intermediate diisocampheylborane. Ipc2BOMe is used as a versatile reagent for the construction of C-C bonds in asymmetric synthesis.
Properties of (+)-B-METHOXYDIISOPINOCAMPHEYLBORANE
| Boiling point: | 365.6±9.0 °C(Predicted) |
| Density | 0.95±0.1 g/cm3(Predicted) |
| Flash point: | >230 °F |
| storage temp. | 2-8°C |
| optical activity | [α]20/D 72±3°, c = 1% in diethyl ether |
Safety information for (+)-B-METHOXYDIISOPINOCAMPHEYLBORANE
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for (+)-B-METHOXYDIISOPINOCAMPHEYLBORANE
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