(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine
Synonym(s):(+)-3,3-Dichloro-2,N-epoxy-exo-10,2-bornanesultam
- CAS NO.：127184-05-8
- Empirical Formula: C10H13Cl2NO3S
- Molecular Weight: 298.19
- MDL number: MFCD00243015
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-06-03 16:17:09
What is (+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine?
Chemical properties
White Solid
The Uses of (+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine
Chiral oxidizing agent.
Purification Methods
Recrystallise the enantiomers from EtOH [Davis & Weismiller J Org Chem 55 3715 1990].
Properties of (+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine
| Melting point: | 181-186 °C |
| Boiling point: | 390.5±52.0 °C(Predicted) |
| Density | 1.68±0.1 g/cm3(Predicted) |
| storage temp. | 2-8°C |
| solubility | Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly) |
| form | Solid |
| pka | -15.63±0.60(Predicted) |
| color | White to Off-White |
| optical activity | [α]20/D +89±3°, c = 0.5% in chloroform |
| BRN | 3653352 |
| InChI | InChI=1/C10H13Cl2NO3S/c1-7(2)6-3-4-8(7)5-17(14,15)13-10(8,16-13)9(6,11)12/h6H,3-5H2,1-2H3/t6-,8-,10+,13?/s3 |
Safety information for (+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine
| Signal word | Danger |
| Pictogram(s) |
 Flame Over Circle Oxidizers GHS03  Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H271:Oxidising liquids;Oxidising solids H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P220:Keep/Store away from clothing/…/combustible materials. P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for (+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine
| InChIKey | HAMBQYFZDBYWHU-XCDSEQPNNA-N |
| SMILES | [C@@]123ON1S(=O)(=O)C[C@@]12CC[C@@]([H])(C1(C)C)C3(Cl)Cl |&1:0,7,10,r| |
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