(-)-MENTHYL CHLORIDE
Synonym(s):(1R)-(−)-Menthyl chloride;(1S,2R,4R)-2-Chloro-1-isopropyl-1-methylcyclohexane;[1S-(1α,2β,4β)]-2-Chloro-4-methyl-1-(methylethyl)cyclohexane
- CAS NO.:16052-42-9
- Empirical Formula: C10H19Cl
- Molecular Weight: 174.71
- MDL number: MFCD00001481
- EINECS: 240-200-7
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-05-25 18:01:14
What is (-)-MENTHYL CHLORIDE?
The Uses of (-)-MENTHYL CHLORIDE
2-Chloro-4-methyl-1-(1-methylethyl)-Cyclohexane is a useful building block for organic synthesis.
Purification Methods
Dissolve menthyl chloride in pet ether (b 40-60o), wash with H2O, conc H2SO4 until no discoloration of the organic layer occurs (care with conc H2SO4 during shaking in a separating funnel), again with H2O and dry it (MgSO4). Evaporate and distil the residual oil through a Claisen head with a Vigreux neck ( p 11) of ca 40 cm length. [Smith & Wright J Org Chem 17 1116 1952, Barton et al. J Chem Soc 453 1952, Beilstein 5 III 134.]
Properties of (-)-MENTHYL CHLORIDE
Melting point: | −20-−16.5 °C(lit.) |
Boiling point: | 101-101.5 °C21 mm Hg(lit.) |
Density | 0.936 g/mL at 25 °C(lit.) |
refractive index | n |
Flash point: | 174 °F |
form | clear liquid |
color | Colorless to Light yellow |
optical activity | [α]20/D 52.4°, neat |
BRN | 1902297 |
Safety information for (-)-MENTHYL CHLORIDE
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H227:Flammable liquids H302:Acute toxicity,oral |
Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P280:Wear protective gloves/protective clothing/eye protection/face protection. P370+P378:In case of fire: Use … for extinction. P403+P235:Store in a well-ventilated place. Keep cool. P501:Dispose of contents/container to..… |
Computed Descriptors for (-)-MENTHYL CHLORIDE
New Products
Rimegepant Impurity 3 Ivermectin EP Impurity B Fosfomycin EP impurity D (2S,4R)-4-amino-2-methyl-5-phenylpentanoic acid hydrochloride Tubulysin A Fuel shell 2-(1-(Mercaptomethyl) cyclopropyl) acetonitrile 2-[2-[3(S)-3[2-(7-chloro-2-quinolinyl) ethenyl] phenyl-3- hydroxyl propyl] phenyl]-2-propanol (1R,2S)-2-(3,4-Difluorophenyl)cyclopropanamine Imeglimin Hydrochloride IH 2-[[(3aR,4S,6R,6aS)-6-Aminotetrahydro-2,2-dimethyl-4H-cyclopenta-1,3-dioxol-4-yl]oxy]ethanol ethanedioate 2-(2,4-Dibutoxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 2-Ethoxy-4-nitrobenzoic acid 3,3,6,6-Tetramethylcyclohexane-1,2-dione 2-(3,5-Di-tert-butylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 2-Chloro-3-(chloromethyl)pyridine 3,6-Bis(4-iodophenyl)-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione 6-Hydroxyisoquinoline 1-(4-Bromophenyl)cyclobutanol Ethyl (2Z)-chloro((4-methoxyphenyl)hydrazono)acetate 5-Amino-3-(4-phenoxyphenyl)-1H-pyrazole-4-carbonitrile N-Boc-(S)-2-amino-3-benzyloxy-1-propanol 7-(1,1-Dimethylethyl) 7-azaspiro[3.5]nonane-2,7-dicarboxylate (2S)-3-Methyl-2-(methylamino)-1-butanolRelated products of tetrahydrofuran
1-CHLORO-5-METHYLHEXANE
Ethylcyclohexane
2-METHYLOCTANE
3-CHLOROPENTANE
2-CHLORO-4-METHYLPENTANE
1-Chlorohexane
3-METHYLOCTANE
ISOPROPYLCYCLOHEXANE
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