(-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE
Synonym(s):(R,R)-Et-DUPHOS-Rh;[(R,R)Ethyl-DuPhosRh(COD)]BF4
- CAS NO.：228121-39-9
- Empirical Formula: C30H46BF4P2Rh
- Molecular Weight: 658.35
- MDL number: MFCD03412155
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE?
The Uses of (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE
(-)-1,2-Bis(2R,5R-2,5-diethylphospholano)benzene)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is a rhodium-based catalyst which is used in asymmetric hydrogenation reactions.
The Uses of (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE
DuPhos and BPE Ligands: Highly Efficient Privileged Ligands
Catalyst for:
- Asymmetric hydrogenation reactions
Properties of (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE
| form | Powder |
| color | Orange to red to brown |
| Sensitive | air sensitive |
| CAS DataBase Reference | 228121-39-9 |
Safety information for (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P280:Wear protective gloves/protective clothing/eye protection/face protection. P337+P313:IF eye irritation persists: Get medical advice/attention. P403+P233:Store in a well-ventilated place. Keep container tightly closed. |
Computed Descriptors for (-)-1,2-BIS((2R,5R)-2,5-DIETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(L)TETRAFLUOROBORATE
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![(-)-1,2-Bis[(2R,5R)-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) tetrafluoroborate](https://img.chemicalbook.in/CAS/GIF/210057-23-1.gif)
![(-)-1,2-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]BENZENE](https://img.chemicalbook.in/CAS/GIF/147253-67-6.gif)
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