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9003-32-1

9003-32-1 structural image
Product Name: POLY(ETHYL ACRYLATE)
Formula: C5H8O2
Synonyms: Acrylic acid ethyl ester polymer;Ethyl acrylate homopolymer
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CHEMICAL AND PHYSICAL PROPERTIES

Physical Description Ethyl acrylate, stabilized appears as a clear colorless liquid with an acrid odor. Flash point 60 °F. May polymerize exothermically if heated or contaminated. If the polymerization takes place inside a container, the container may rupture violently. Auto ignition temperature 721 °F (383 °C) (NTP). Less dense than water. Vapors heavier than air. Used to make paints and plastics.
Color/Form Colorless liquid
Odor Acrid penetrating odor
Boiling Point 211.6 °F at 760 mmHg (NTP, 1992)
Melting Point -96.2 °F (NTP, 1992)
Flash Point 48 °F (NTP, 1992)
Solubility 10 to 50 mg/mL at 70 °F (NTP, 1992)
Density 0.923 at 68 °F (USCG, 1999) - Less dense than water; will float
Vapor Density 3.45 (NTP, 1992) - Heavier than air; will sink (Relative to Air)
Vapor Pressure 29.3 mmHg at 68 °F ; 40 mmHg at 79 °F (NTP, 1992)
LogP log Kow = 1.32
Stability/Shelf Life Easily polymerizes on standing; polymerization process speeded up by heat, light, and peroxides. If pure, the monomer can be stored below +10 °C without incurring polymerization.
Autoignition Temperature 721 °F (USCG, 1999)
Decomposition When heated to decomp it emits acrid smoke and irritating fumes.
Heat of Combustion 655.49 kcal/mol
Heat of Vaporization 8.27 kcal/mol
Surface Tension 0.025 DYNES/CM= 0.025 N/M @ 20 °C
Ionization Potential 10.30 eV
Polymerization Hazardous polymerization may occur. Polymerization may be caused by elevated temperature, oxidizers, peroxides ... Uninhibited monomer vapor may form polymer in vents and other confined spaces. /Ethyl acrylate, inhibited/
Odor Threshold Odor Threshold Low: 0.0002 [mmHg] Odor Threshold High: 0.0013 [mmHg] Detection odor threshold from AIHA (mean = 0.00024 ppm)
Refractive Index Index of refraction: 1.4068 at 20 °C/D
Relative Evaporation Rate 3.3 (butyl acetate= 1)
Kovats Retention Index 678 683 676 678 681 680 676 684 664 664 681 681 677.6 675.1 682.8 664 677
Other Experimental Properties Polymerizes on standing; polymerization process speeded up by heat, light, and peroxides. If pure, the monomer can be stored below +10 °C without polymerization.
Chemical Classes Plastics & Rubber -> (Meth)acrylates

SAFETY INFORMATION

Signal word Danger
Pictogram(s)

Flame
Flammables
GHS02

Exclamation Mark
Irritant
GHS07

Health Hazard
GHS08
GHS Hazard Statements H225:Flammable liquids
H304:Aspiration hazard
H315:Skin corrosion/irritation
H336:Specific target organ toxicity,single exposure; Narcotic effects
H373:Specific target organ toxicity, repeated exposure
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P281:Use personal protective equipment as required.
P331:Do NOT induce vomiting.
P301+P310:IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

COMPUTED DESCRIPTORS

Molecular Weight 100.12 g/mol
XLogP3 1.3
Hydrogen Bond Donor Count 0
Hydrogen Bond Acceptor Count 2
Rotatable Bond Count 3
Exact Mass 100.052429494 g/mol
Monoisotopic Mass 100.052429494 g/mol
Topological Polar Surface Area 26.3 Ų
Heavy Atom Count 7
Formal Charge 0
Complexity 76.1
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
Covalently-Bonded Unit Count 1
Compound Is Canonicalized Yes

PRODUCT INTRODUCTION

description

Ethyl acrylate, stabilized appears as a clear colorless liquid with an acrid odor. Flash point 60 °F. May polymerize exothermically if heated or contaminated. If the polymerization takes place inside a container, the container may rupture violently. Auto ignition temperature 721 °F (383 °C) (NTP). Less dense than water. Vapors heavier than air. Used to make paints and plastics.