87413-09-0
Product Name:
Dess-Martin periodinane
Formula:
C13H13IO8
Synonyms:
1,1,1-Tris(acetyloxy)-1,1-dihydro-1,2-benziodoxol-3-(1H)-one
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SAFETY INFORMATION
| Signal word | Danger |
|---|---|
| Pictogram(s) |
 Flame Over Circle Oxidizers GHS03  Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H272:Oxidising liquids;Oxidising solids H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P220:Keep/Store away from clothing/…/combustible materials. P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
COMPUTED DESCRIPTORS
| Molecular Weight | 424.14 g/mol |
|---|---|
| XLogP3 | 2.7 |
| Hydrogen Bond Donor Count | 0 |
| Hydrogen Bond Acceptor Count | 8 |
| Rotatable Bond Count | 6 |
| Exact Mass | 423.96551 g/mol |
| Monoisotopic Mass | 423.96551 g/mol |
| Topological Polar Surface Area | 105 Ų |
| Heavy Atom Count | 22 |
| Formal Charge | 0 |
| Complexity | 499 |
| Isotope Atom Count | 0 |
| Defined Atom Stereocenter Count | 0 |
| Undefined Atom Stereocenter Count | 0 |
| Defined Bond Stereocenter Count | 0 |
| Undefined Bond Stereocenter Count | 0 |
| Covalently-Bonded Unit Count | 1 |
| Compound Is Canonicalized | Yes |
PRODUCT INTRODUCTION
Description
Dess-Martin periodinane (DMP), a broadly applicable oxidant, is a hypervalent iodine reagent used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. This reagent is attractive because of its operation under mild conditions (room temperature, neutral pH), short reaction times, higher yields, simple work-ups, high chemoselectivity, tolerance of sensitive functional groups, and long shelf life. The presence of acetate groups makes DMP more soluble in a broader range of solvents than the IBX reagent.
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