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87413-09-0

87413-09-0 structural image
Product Name: Dess-Martin periodinane
Formula: C13H13IO8
Synonyms: 1,1,1-Tris(acetyloxy)-1,1-dihydro-1,2-benziodoxol-3-(1H)-one
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SAFETY INFORMATION

Signal word Danger
Pictogram(s)

Flame Over Circle
Oxidizers
GHS03

Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H272:Oxidising liquids;Oxidising solids
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P220:Keep/Store away from clothing/…/combustible materials.
P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

COMPUTED DESCRIPTORS

Molecular Weight 424.14 g/mol
XLogP3 2.7
Hydrogen Bond Donor Count 0
Hydrogen Bond Acceptor Count 8
Rotatable Bond Count 6
Exact Mass 423.96551 g/mol
Monoisotopic Mass 423.96551 g/mol
Topological Polar Surface Area 105 Ų
Heavy Atom Count 22
Formal Charge 0
Complexity 499
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
Covalently-Bonded Unit Count 1
Compound Is Canonicalized Yes

PRODUCT INTRODUCTION

Description

Dess-Martin periodinane (DMP), a broadly applicable oxidant, is a hypervalent iodine reagent used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. This reagent is attractive because of its operation under mild conditions (room temperature, neutral pH), short reaction times, higher yields, simple work-ups, high chemoselectivity, tolerance of sensitive functional groups, and long shelf life. The presence of acetate groups makes DMP more soluble in a broader range of solvents than the IBX reagent.

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