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7727-18-6

7727-18-6 structural image
Product Name: VANADIUM(V) TRICHLORIDE OXIDE
Formula: Cl3OV
Synonyms: Trichlorooxovanadium oxide;Vanadium(V) oxytrichloride;Vanadyl trichloride
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CHEMICAL AND PHYSICAL PROPERTIES

Physical Description Vanadium oxytrichloride appears as a lemon yellow liquid. Boiling point 257-260 °F (125-127 °C). Corrosive to metals and tissue. Used as a catalyst.
Color/Form Lemon-yellow liquid
Odor Sharp unpleasant odor
Boiling Point 259 °F at 760 mmHg (USCG, 1999)
Melting Point -107 °F (USCG, 1999)
Solubility Reacts with water
Density 1.83 at 68 °F (USCG, 1999) - Denser than water; will sink
Vapor Density 5.98 (Air = 1)
Vapor Pressure 19.3 [mmHg]
Stability/Shelf Life Stable.
Decomposition Hazardous Decomposition Products: Hydrogen chloride gas.
Corrosivity In presence of moisture will corrode most metals
Heat of Vaporization Enthalpy of vaporization = 36.78 kJ/mol at 127 °C
Refractive Index Index of refraction: 1.63
Other Experimental Properties Decomposes in presence of moisture into vanadic acid and HCl. When a small quantity of water is added, it becomes thick and almost blood-red because of formation of vanadic acid.
Chemical Classes Metals -> Metals, Inorganic Compounds

SAFETY INFORMATION

Signal word Danger
Pictogram(s)

Corrosion
Corrosives
GHS05

Skull and Crossbones
Acute Toxicity
GHS06
GHS Hazard Statements H301:Acute toxicity,oral
H314:Skin corrosion/irritation
Precautionary Statement Codes P270:Do not eat, drink or smoke when using this product.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P363:Wash contaminated clothing before reuse.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

COMPUTED DESCRIPTORS

Molecular Weight 176.32 g/mol
Hydrogen Bond Donor Count 3
Hydrogen Bond Acceptor Count 1
Rotatable Bond Count 0
Exact Mass 174.868905 g/mol
Monoisotopic Mass 174.868905 g/mol
Topological Polar Surface Area 17.1 Ų
Heavy Atom Count 5
Formal Charge 0
Complexity 6.9
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
Covalently-Bonded Unit Count 4
Compound Is Canonicalized Yes

PRODUCT INTRODUCTION

description

Vanadium oxytrichloride appears as a lemon yellow liquid. Boiling point 257-260 °F (125-127 °C). Corrosive to metals and tissue. Used as a catalyst.