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75-69-4

75-69-4 structural image
Product Name: Trichlorofluoromethane
Formula: CCl3F
Synonyms: CFC-11;Fluorotrichloromethane;Freon 11
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CHEMICAL AND PHYSICAL PROPERTIES

Physical Description Trichlorofluoromethane appears as a clear light colored liquid. Nearly odorless. Denser than water. Poses low acute health hazard to humans. Primary hazard is to the environment. Immediate steps should be taken to limit spread to the environment. Easily penetrates the soil to contaminate groundwater and nearby waterways.
Color/Form Volatile liquid or gas
Odor In concentration of less than 20% (by volume in air), trichlorofluoromethane is odorless, in higher concentration, its odor is mild and somewhat ethereal.
Boiling Point 74.7 °F at 760 mmHg (NTP, 1992)
Melting Point -168 °F (NTP, 1992)
Solubility 10 to 50 mg/mL at 64 °F (NTP, 1992)
Density 1.49 at 63 °F (NTP, 1992) - Denser than water; will sink
Vapor Density 5.04 at 77 °F (NTP, 1992) - Heavier than air; will sink (Relative to Air)
Vapor Pressure 792 mmHg at 77 °F (NTP, 1992)
LogP log Kow = 2.53
Henry's Law Constant Henry's Law constant = 9.70X10-2 atm-cu cm/mol at 25 °C
Stability/Shelf Life The product is normally stable.
Autoignition Temperature Not flammable (USCG, 1999)
Decomposition Decomposition products include hydrochloric acid, hydrofluoric acid, and carbonyl halides.
Viscosity Gas: 0.0105 mPa.s at 24 °C; liquid: 0.43 mPa.s at 20 °C
Corrosivity Liquid fluorotrichloromethane will attack some forms of plastics, rubber, and coatings.
Heat of Vaporization 25.1 kJ/mol at 23.7 °C
Surface Tension 18 dyn/cm at 25 °C
Ionization Potential 11.77 eV
Odor Threshold Odor Threshold Low: 200000.0 [mmHg] Odor threshold is 200,000 ppm (20% by volume). [CHEMINFO] VP from HSDB
Refractive Index Index of refraction: 1.3865 @ 18.5 °C/D
Relative Evaporation Rate 63 (Butyl acetate = 1)
Kovats Retention Index 470 486 486 482 474.9 478 478 484 475.9 484
Other Experimental Properties Global warming potential: 1.0; ozone depletion potential: 1.0
Chemical Classes Solvents -> Chlorofluorocarbons

SAFETY INFORMATION

Signal word Danger
Pictogram(s)

Skull and Crossbones
Acute Toxicity
GHS06

Health Hazard
GHS08
GHS Hazard Statements H302:Acute toxicity,oral
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H331:Acute toxicity,inhalation
H336:Specific target organ toxicity,single exposure; Narcotic effects
H351:Carcinogenicity
H372:Specific target organ toxicity, repeated exposure
H420:Hazardous to the ozone layer
Precautionary Statement Codes P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313:IF exposed or concerned: Get medical advice/attention.
P502:Refer to manufacturer/supplier for information on recovery/recycling

COMPUTED DESCRIPTORS

Molecular Weight 137.36 g/mol
XLogP3 2.5
Hydrogen Bond Donor Count 0
Hydrogen Bond Acceptor Count 1
Rotatable Bond Count 0
Exact Mass 135.904961 g/mol
Monoisotopic Mass 135.904961 g/mol
Topological Polar Surface Area 0 Ų
Heavy Atom Count 5
Formal Charge 0
Complexity 28.4
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
Covalently-Bonded Unit Count 1
Compound Is Canonicalized Yes

PRODUCT INTRODUCTION

description

Trichlorofluoromethane appears as a clear light colored liquid. Nearly odorless. Denser than water. Poses low acute health hazard to humans. Primary hazard is to the environment. Immediate steps should be taken to limit spread to the environment. Easily penetrates the soil to contaminate groundwater and nearby waterways.