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75-63-8

75-63-8 structural image
Product Name: BROMOTRIFLUOROMETHANE
Formula: CBrF3
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CHEMICAL AND PHYSICAL PROPERTIES

Physical Description Bromotrifluoromethane appears as a colorless, odorless gas at room conditions Shipped as a liquid confined under its own vapor pressure. Noncombustible. Nontoxic but can asphyxiate by the displacement of air. Contact with the unconfined liquid can cause frostbite by evaporative cooling. Exposure of the container to prolonged heat or fire can cause it to rupture violently and rocket.
Color/Form Colorless gas [Note: Shipped as a liquefied compressed gas.]
Odor Odorless gas.
Boiling Point -72 °F at 760 mmHg (NIOSH, 2023)
Melting Point -267 °F (NIOSH, 2023)
Solubility 0.03 % (NIOSH, 2023)
Density 1.5800 g/ml @ 20 °C (liq)
Vapor Density 5.14 (NIOSH, 2023) - Heavier than air; will sink (Relative to Air)
Vapor Pressure greater than 1 atm (NIOSH, 2023)
LogP log Kow= 1.86
Henry's Law Constant Henry's Law constant= 0.4994 atm-cu m/mole at 25 °C
Stability/Shelf Life Conditions contributing to instability: heat
Decomposition THE FIRE EXTINGUISHER HALON 1301 BEGINS TO DECOMP AT 400-500 DEG TO HALOGEN GASES, WHICH REACT WITH HYDROGEN TO FORM HYDROGEN HALIDES. IN OXYGEN, CARBON DIOXIDE, CARBONYL FLUORIDE & CARBONYL BROMIDE MAY FORM. HAZARDS FROM DECOMP PRODUCTS ARE NEGLIGIBLE AS COMPARED TO THOSE OF OTHER HAZARDS ASSOCIATED WITH A FIRE.
Viscosity 0.157 mPa.s @ 25 °C (liq); 0.0154 mPa.s @ 25 °C - 101.3 kPa (vapor)
Corrosivity Noncorrosive
Heat of Vaporization 118.7 kJ/kg @ boiling point
Surface Tension 4 mN/m @ 25 °C
Ionization Potential 11.78 eV
Refractive Index Index of refraction: 1.238 @ 25 °C/D
Kovats Retention Index 222 222
Other Experimental Properties Ionization potential: 11.78
Chemical Classes Solvents -> Chlorofluorocarbons

COMPUTED DESCRIPTORS

Molecular Weight 148.91 g/mol
XLogP3 2.2
Hydrogen Bond Donor Count 0
Hydrogen Bond Acceptor Count 3
Rotatable Bond Count 0
Exact Mass 147.91355 g/mol
Monoisotopic Mass 147.91355 g/mol
Topological Polar Surface Area 0 Ų
Heavy Atom Count 5
Formal Charge 0
Complexity 28.4
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
Covalently-Bonded Unit Count 1
Compound Is Canonicalized Yes

PRODUCT INTRODUCTION

description

Bromotrifluoromethane appears as a colorless, odorless gas at room conditions Shipped as a liquid confined under its own vapor pressure. Noncombustible. Nontoxic but can asphyxiate by the displacement of air. Contact with the unconfined liquid can cause frostbite by evaporative cooling. Exposure of the container to prolonged heat or fire can cause it to rupture violently and rocket.