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13770-96-2

13770-96-2 structural image
Product Name: Sodium aluminium hydride
Formula: Na.AlH4
Synonyms: Sodium tetrahydroaluminate
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CHEMICAL AND PHYSICAL PROPERTIES

Physical Description Sodium aluminum hydride appears as a white crystalline solid. Density 1.24 g / cm3. If spread over a large flat combustible area, friction can ignite the material. Soluble in tetrahydrofuran.
Color/Form White crystalline material
Melting Point Begins to melt at 183 °C with decomposition to evolve hydrogen
Solubility Soluble in tetrahydrofuran, dimethyl "Cellosolve"
Density 1.24
Stability/Shelf Life Stable in dry air at room temperature but sensitive to moisture.
Decomposition When heated to decomposition it emits toxic fumes of /disodium oxide/.
Other Experimental Properties Stable in dry air but sensitive to moisture.
Chemical Classes Metals -> Metal Hydrides

SAFETY INFORMATION

Signal word Danger
Pictogram(s)

Flame
Flammables
GHS02

Corrosion
Corrosives
GHS05

Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H261:Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases
H302:Acute toxicity,oral
H314:Skin corrosion/irritation
Precautionary Statement Codes P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P231+P232:Handle under inert gas. Protect from moisture.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

COMPUTED DESCRIPTORS

Molecular Weight 54.003 g/mol
Hydrogen Bond Donor Count 0
Hydrogen Bond Acceptor Count 1
Rotatable Bond Count 0
Exact Mass 54.0026078 g/mol
Monoisotopic Mass 54.0026078 g/mol
Topological Polar Surface Area 0 Ų
Heavy Atom Count 2
Formal Charge 0
Complexity 0
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
Covalently-Bonded Unit Count 2
Compound Is Canonicalized Yes

PRODUCT INTRODUCTION

description

Sodium aluminum hydride appears as a white crystalline solid. Density 1.24 g / cm3. If spread over a large flat combustible area, friction can ignite the material. Soluble in tetrahydrofuran.