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1336-21-6

1336-21-6 structural image
Product Name: Ammonium hydroxide
Formula: H5NO
Synonyms: Ammonia aqueous;Ammonia Solution;Ammonia water;Ammonium hydroxide solution;Ammonium hydroxide solution, Ammonia water
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CHEMICAL AND PHYSICAL PROPERTIES

Physical Description Ammonium hydroxide appears as a colorless aqueous solution. Concentration of ammonia ranges up to approximately 30%. Ammonia vapors (which arise from the solution) irritate the eyes.
Color/Form Colorless liquid
Odor Intense, pungent, suffocating odor
Taste Acrid taste
Boiling Point 38 °C (25%)
Melting Point -58 °C (25%)
Solubility Exists only in solution
Density About 0.90 @ 25 °C/25 °C
Vapor Density Relative vapor density (air = 1): 0.6
Vapor Pressure 2160 mm Hg @ 25 °C
Decomposition When heated to decomposition it emits ammonia and nitroxides.
Corrosivity Dissolves copper, zinc
pH pH= 11.6 (1.0 N solution); 11.1 (0.1 N solution); 10.6 (0.01 N solution)
Odor Threshold Odor Threshold Low: 50.0 [ppm] [HSDB] Odor threshold from CHRIS
Dissociation Constants pKb= 4.767, Kb= 1.710X10-5 at 20 °C; pKb= 4.751, Kb= 1.774X10-5 at 25 °C; pKb= 4.740, Kb= 1.820X10-5 at 30 °C
Other Experimental Properties Reaction with sulfuric acid or other strong mineral acids is exothermic; mixture becomes boiling hot
Chemical Classes Other Classes -> Bases

SAFETY INFORMATION

Signal word Danger
Pictogram(s)

Corrosion
Corrosives
GHS05

Exclamation Mark
Irritant
GHS07

Environment
GHS09
GHS Hazard Statements H314:Skin corrosion/irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
H410:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P271:Use only outdoors or in a well-ventilated area.
P273:Avoid release to the environment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

COMPUTED DESCRIPTORS

Molecular Weight 35.046 g/mol
Hydrogen Bond Donor Count 2
Hydrogen Bond Acceptor Count 1
Rotatable Bond Count 0
Exact Mass 35.037113783 g/mol
Monoisotopic Mass 35.037113783 g/mol
Topological Polar Surface Area 2 Ų
Heavy Atom Count 2
Formal Charge 0
Complexity 0
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
Covalently-Bonded Unit Count 2
Compound Is Canonicalized Yes

PRODUCT INTRODUCTION

description

Ammonium hydroxide appears as a colorless aqueous solution. Concentration of ammonia ranges up to approximately 30%. Ammonia vapors (which arise from the solution) irritate the eyes.

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