75-59-2
Product Name:
Tetramethylammonium hydroxide
Formula:
C4H13NO
Synonyms:
TMAH solution
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CHEMICAL AND PHYSICAL PROPERTIES
Physical Description | Tetramethylammonium hydroxide is a solid in the hydrated form or a colorless liquid with a strong ammonia-like odor. It is soluble in water. It is corrosive to metals and tissue. |
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Color/Form | The free base is known only in solution or as a solid pentahydrate, forming colorless, deliquescent needles |
Odor | Strong ammonia-like |
Melting Point | 63 °C |
Density | Specific gravity of solution approximately 1.00 at 24 °C/4 °C |
Stability/Shelf Life | Stable under recommended storage conditions. /Tetramethylammonium hydroxide pentahydrate/ |
Decomposition | When heated to decomposition it emits toxic fumes of /nitrogen oxides and ammonia/. |
Corrosivity | Corrosive |
Other Experimental Properties | Decomposes to trimethylamine and methanol upon distillation |
Chemical Classes | Other Classes -> Bases |
SAFETY INFORMATION
Signal word | Danger |
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Pictogram(s) |
Flame Flammables GHS02 Corrosion Corrosives GHS05 Skull and Crossbones Acute Toxicity GHS06 Health Hazard GHS08 |
GHS Hazard Statements |
H226:Flammable liquids H314:Skin corrosion/irritation H331:Acute toxicity,inhalation H370:Specific target organ toxicity, single exposure H372:Specific target organ toxicity, repeated exposure H412:Hazardous to the aquatic environment, long-term hazard |
Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
COMPUTED DESCRIPTORS
Molecular Weight | 91.15 g/mol |
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Hydrogen Bond Donor Count | 1 |
Hydrogen Bond Acceptor Count | 1 |
Rotatable Bond Count | 0 |
Exact Mass | 91.099714038 g/mol |
Monoisotopic Mass | 91.099714038 g/mol |
Topological Polar Surface Area | 1 Ų |
Heavy Atom Count | 6 |
Formal Charge | 0 |
Complexity | 19.1 |
Isotope Atom Count | 0 |
Defined Atom Stereocenter Count | 0 |
Undefined Atom Stereocenter Count | 0 |
Defined Bond Stereocenter Count | 0 |
Undefined Bond Stereocenter Count | 0 |
Covalently-Bonded Unit Count | 2 |
Compound Is Canonicalized | Yes |
PRODUCT INTRODUCTION
description
Tetramethylammonium hydroxide is a solid in the hydrated form or a colorless liquid with a strong ammonia-like odor. It is soluble in water. It is corrosive to metals and tissue.
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