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8014-95-7

8014-95-7 structural image
Product Name: FUMING SULFURIC ACID
Formula: H2O7S2
Synonyms: Oleum
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CHEMICAL AND PHYSICAL PROPERTIES

Physical Description Thick fuming yellow liquid. Density 16.5 lb / gal. Very toxic by inhalation. Corrosive to metals and tissue, quickly causing severe burns. Used to make chemicals, dyes, explosives and in petroleum refining.
Color/Form Colorless or slightly colored, viscous liquid
Solubility Solubility in water: miscible, reaction
Density 1.91 to 1.97 at 59 °F (USCG, 1999)
Vapor Density Relative vapor density (air = 1): 3-3.3
Vapor Pressure approximately 20 kPa at 40 °C /50% SO3, wt % (% Oleum)/
Autoignition Temperature Not flammable (USCG, 1999)
Decomposition When heated to decomposition it emits highly toxic fumes of oxides of /sulfur oxide/.
Viscosity 38 mPa-sec at 25 °C /30% SO3, wt % (% Oleum)/
Corrosivity Extremely corrosive
Other Experimental Properties 38 mPa-sec at 25 °C /30% SO3, wt % (% Oleum)/
Chemical Classes Toxic Gases & Vapors -> Acids, Inorganic

SAFETY INFORMATION

Signal word Danger
Pictogram(s)

Corrosion
Corrosives
GHS05

Skull and Crossbones
Acute Toxicity
GHS06
GHS Hazard Statements H314:Skin corrosion/irritation
H330:Acute toxicity,inhalation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

COMPUTED DESCRIPTORS

Molecular Weight 178.15 g/mol
Hydrogen Bond Donor Count 2
Hydrogen Bond Acceptor Count 7
Rotatable Bond Count 0
Exact Mass 177.92419475 g/mol
Monoisotopic Mass 177.92419475 g/mol
Topological Polar Surface Area 135 Ų
Heavy Atom Count 9
Formal Charge 0
Complexity 143
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
Covalently-Bonded Unit Count 2
Compound Is Canonicalized Yes

PRODUCT INTRODUCTION

description

Thick fuming yellow liquid. Density 16.5 lb / gal. Very toxic by inhalation. Corrosive to metals and tissue, quickly causing severe burns. Used to make chemicals, dyes, explosives and in petroleum refining.