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2867-47-2

2867-47-2 structural image
Product Name: 2-(Dimethylamino)ethyl methacrylate
Formula: C8H15NO2
Synonyms: (2-Dimethylaminoethyl) methacrylate;2-Propenoic acid-2-methyl-(2-dimethylamino)ethylester;Methacrylic acid 2-(dimethylamino)ethyl ester
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CHEMICAL AND PHYSICAL PROPERTIES

Physical Description 2-dimethylaminoethyl methacrylate appears as a clear colorless liquid. Less dense than water and insoluble in water. Vapors heavier than air and corrosive to eyes and mucous membranes. May polymerize exothermically if heated or contaminated. If polymerization takes place inside a closed container, the container may rupture violently. Produces toxic oxides of nitrogen during combustion. Toxic by skin absorption, ingestion and inhalation. Used to make plastics and in textiles.
Color/Form Liquid
Odor Amine-like
Boiling Point 186 °C
Melting Point -30 °C (freezing point)
Flash Point 165 °F (NFPA, 2010)
Solubility In water, 1000 g/L at 20 °C (study performed without adjustment of pH value)
Density Specific gravity: 0.933 at 25 °C
Vapor Density 5.4 (AIR= 1)
Vapor Pressure 0.82 [mmHg]
LogP log Kow = 1.13 at 25 °C; OECD Guideline 107 (Partition Coefficient (n-octanol/water), Shake Flask Method)
Autoignition Temperature 255 °C
Decomposition When heated to decomposition it emits toxic fumes of nitroxides.
Viscosity 1.34 mPa s at 25 °C
Heat of Vaporization 48.8 kJ/mol
Polymerization METHYL METHACRYLATE, AND IN GENERAL THE METHACRYLIC ESTERS, POLYMERIZE MUCH LESS READILY THAN THE CORRESPONDING ORDINARY ACRYLATES. NONE THE LESS, THEY ARE STABILIZED BY ADDING HYDROQUINONE OR PYROGALLOL, PARTICULARLY IN THE PRESENCE OF METALLIC COPPER. /METHACRYLATES/
Refractive Index Index of refraction: 1.4396 at 20 °C
Dissociation Constants pKa = 8.44 at 25 °C
Other Experimental Properties Most aliphatic amines have an unpleasant, fishy or fishlike odor and in high concentrations they all have the odor of ammonia. /Aliphatic amines/
Chemical Classes Plastics & Rubber -> (Meth)acrylates

SAFETY INFORMATION

Signal word Danger
Pictogram(s)

Corrosion
Corrosives
GHS05

Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H314:Skin corrosion/irritation
H317:Sensitisation, Skin
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P270:Do not eat, drink or smoke when using this product.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

COMPUTED DESCRIPTORS

Molecular Weight 157.21 g/mol
XLogP3 1.2
Hydrogen Bond Donor Count 0
Hydrogen Bond Acceptor Count 3
Rotatable Bond Count 5
Exact Mass 157.110278721 g/mol
Monoisotopic Mass 157.110278721 g/mol
Topological Polar Surface Area 29.5 Ų
Heavy Atom Count 11
Formal Charge 0
Complexity 152
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
Covalently-Bonded Unit Count 1
Compound Is Canonicalized Yes

PRODUCT INTRODUCTION

description

2-dimethylaminoethyl methacrylate appears as a clear colorless liquid. Less dense than water and insoluble in water. Vapors heavier than air and corrosive to eyes and mucous membranes. May polymerize exothermically if heated or contaminated. If polymerization takes place inside a closed container, the container may rupture violently. Produces toxic oxides of nitrogen during combustion. Toxic by skin absorption, ingestion and inhalation. Used to make plastics and in textiles.