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868-77-9

868-77-9 structural image
Product Name: 2-Hydroxyethyl methacrylate
Formula: C6H10O3
Synonyms: 1,2-Ethanediol mono(2-methylpropenoate);2-Hydroxyethyl 2-methylpropenoate, HEMA, Methacrylic acid 2-hydroxyethyl ester;2-Hydroxyethyl methacrylate;Glycol methacrylate;HEMA
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CHEMICAL AND PHYSICAL PROPERTIES

Physical Description Liquid
Color/Form Clear mobile liquid
Boiling Point 67 °C @ 3.5 mm Hg
Melting Point FP: -12 °C
Flash Point 97 °C (closed cup)
Solubility Miscible with water and soluble in common org solvents
Density 1.034 @ 25 °C/4 °C
Vapor Density Relative vapor density (air = 1): 4.5
Vapor Pressure 0.12 [mmHg]
LogP log Kow= 0.47
Stability/Shelf Life AN INHIBITOR IS USUALLY ADDED TO SOLUTIONS TO PROLONG SHELF LIFE.
Decomposition When heated to decomp it emits acrid smoke and irritating fumes.
Viscosity 8.4 mm²/s at 20 °C
Polymerization METHYL METHACRYLATE, AND IN GENERAL THE METHACRYLIC ESTERS, POLYMERIZE MUCH LESS READILY THAN THE CORRESPONDING ORDINARY ACRYLATES. NONE THE LESS, THEY ARE STABILIZED BY ADDING HYDROQUINONE OR PYROGALLOL, PARTICULARLY IN THE PRESENCE OF METALLIC COPPER. /METHACRYLATES/
Refractive Index Index of refraction: 1.4515 @ 20 °C/D
Kovats Retention Index 985.1
Other Experimental Properties Heat of polymerization: 49.8 kJ/mole
Chemical Classes Plastics & Rubber -> (Meth)acrylates

SAFETY INFORMATION

Signal word Warning
Pictogram(s)

Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H317:Sensitisation, Skin
H319:Serious eye damage/eye irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P272:Contaminated work clothing should not be allowed out of the workplace.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

COMPUTED DESCRIPTORS

Molecular Weight 130.14 g/mol
XLogP3 0.5
Hydrogen Bond Donor Count 1
Hydrogen Bond Acceptor Count 3
Rotatable Bond Count 4
Exact Mass 130.062994177 g/mol
Monoisotopic Mass 130.062994177 g/mol
Topological Polar Surface Area 46.5 Ų
Heavy Atom Count 9
Formal Charge 0
Complexity 118
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
Covalently-Bonded Unit Count 1
Compound Is Canonicalized Yes

PRODUCT INTRODUCTION

description

2-hydroxyethyl methacrylate is an enoate ester that is the monomethacryloyl derivative of ethylene glycol. It has a role as a polymerisation monomer and an allergen. It is functionally related to an ethylene glycol and a methacrylic acid.

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