Tris(triphenylphosphine)rhodiu
Synonym(s):NSC 124140;RhCl(PPh3)3;Rhodium(I) tris(triphenylphosphine) chloride;Wilkinson’s catalyst
- CAS NO.：14694-95-2
- Empirical Formula: C54H45ClP3Rh
- Molecular Weight: 925.21
- MDL number: MFCD00010016
- EINECS: 238-744-5
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-12-14 20:49:34
What is Tris(triphenylphosphine)rhodiu?
The Uses of Tris(triphenylphosphine)rhodiu
Tris(triphenylphosphine)rhodiu is also known as Wilkinson's catalyst and is commonly used to catalyze the hydrogenation of alkenes. Tris(triphenylphosphine)rhodiu is also used in the catalytic hydroboration of alkenes with catecholborane and pinacolborane and the selective 1,4-reduction of α, β-unsaturated carbonyl compounds.
Properties of Tris(triphenylphosphine)rhodiu
| Melting point: | 245-250 °C (dec.) |
| Boiling point: | >170°C |
| Density | 1.363; d 1.379 |
| storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
| solubility | Soluble in most solvents (e.g. benzene, ethanol, chloroform, dichloromethane) but with phosphine dissociation. Reacts with O{2} in solution |
| form | Crystalline Powder |
| color | Red-brown to maroon |
| Water Solubility | insoluble |
| Sensitive | air sensitive |
Safety information for Tris(triphenylphosphine)rhodiu
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H317:Sensitisation, Skin H413:Hazardous to the aquatic environment, long-term hazard |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P272:Contaminated work clothing should not be allowed out of the workplace. P273:Avoid release to the environment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P333+P313:IF SKIN irritation or rash occurs: Get medical advice/attention. |
Computed Descriptors for Tris(triphenylphosphine)rhodiu
| InChIKey | QEYYHUJFSQCTAE-UHFFFAOYSA-M |
Abamectin manufacturer
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SOLFYN INTERNATIONAL LLP
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Johnson Matthey Chemicals India Pvt Ltd
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