TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE
Synonym(s):DMPP
- CAS NO.:85417-41-0
- Empirical Formula: C24H27O6P
- Molecular Weight: 442.44
- MDL number: MFCD00192558
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-05-11 17:26:00
What is TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE?
The Uses of TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE
Catalyst for:
- Preparation of chiral building blocks via hydroalkynylation reactions or ynolates
- Three-component aza-Morita-Baylis-Hillman reactions (aza-MBH)
- Atom-economic synthesis of nitrogen heterocycles and ynenoates from alkynes
- Oxycylizations of allendiols
- Enantioselective aldol reactions
- Pd-mediated cross-coupling, Pd- and Cu-mediated benzannulation reactions and copper-mediated dimerization reactions
Properties of TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE
Melting point: | 145-147 °C(lit.) |
Boiling point: | 566.4±50.0 °C(Predicted) |
storage temp. | Sealed in dry,Room Temperature |
solubility | very faint turbidity in hot Methanol |
form | Powder |
color | white to off-white |
Sensitive | air sensitive |
Safety information for TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. |
Computed Descriptors for TRIS(2,6-DIMETHOXYPHENYL)PHOSPHINE
New Products
3-N-BOC-(S)-AMINO BUTYRONITRILE 4-Piperidinopiperidine N-Benzyl-3-hydroxypiperidine 2-Methyl-4-nitrobenzoic acid 2-(4-bromophenyl)-2-methylpropanoic acid 4-Acetyl-2-methylbenzoicacid Acetyl-meldrum's acid Ethyl-4-Pyrazole carboxylate 2,6-Pyridinedimethanol 5,7-Dichloro-3H-Imidazo[4,5-B]Pyridine 5-Bromo-2-Methoxy-4-Methyl-3-Nitropyridine 2-Fluoro-5-Iodopyridine 2-Fluoro-5-Methylpyridine 2-Chloro-3-Bromo-5-Amiopyridine METHYL-4-(BUTYRYLAMINO)3-METHYL-5-NITROBENZOATE TRANS-CYCLOBUTANE-1,2- DICARBOXYLIC ACID 5-Nitro indazole R-(-)-5-(2-AMINO-PROPYL)-2-METHOXY-BENZENESULFONAMIDE 1,3-cyclohexanedione 4-Aminophenaethylalchol (S)-(+)-4-BENZYL-2-OXAZOLIDINONE 3-NITRO-5-ACETYL IMINODIBENZYL 4-FLUORO PHENYL MAGNESIUM BROMIDE 1.0 M IN THF 1-HYDROXY-4-METHYL6-(2,4,4-TRI METHYL PHENYL)-2-PYRIDONE MONO ETHANOL AMINE(PIROCTONE OLAMINE)Related products of tetrahydrofuran
TRIS(2-METHOXYPHENYL)PHOSPHINE
TRIS(2,4-DIMETHYLPHENYL)PHOSPHINE
TRIS(3-METHOXYPHENYL)PHOSPHINE
tris(2-fluorophenyl)phosphane
Tris(4-fluorophenyl)phosphine
DIPHENYL(O-TOLYL)PHOSPHINE
TRIS(3,5-DIMETHYLPHENYL)PHOSPHINE
TRIS(4-METHOXYPHENYL)PHOSPHINE
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