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HomeProduct name listTrifluoromethanesulfonic anhydride

Trifluoromethanesulfonic anhydride

Synonym(s):Perfluoromethanesulfonic anhydride solution;Tf2O;Triflic anhydride;Triflic anhydride solution;Trifluoromethanesulfonic anhydride

  • CAS NO.:358-23-6
  • Empirical Formula: C2F6O5S2
  • Molecular Weight: 282.14
  • MDL number: MFCD00000408
  • EINECS: 206-616-8
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-05-15 13:45:27
Trifluoromethanesulfonic anhydride Structural Picture

What is Trifluoromethanesulfonic anhydride?

The Uses of Trifluoromethanesulfonic anhydride

Trifluoromethanesulfonic Anhydride is a strong electrophile used in chemical synthesis for introducing the triflyl group.

Properties of Trifluoromethanesulfonic anhydride

Melting point: -80°C
Boiling point: 81-83 °C (lit.)
Density  1.677 g/mL at 25 °C (lit.)
Flash point: 81-83°C
storage temp.  Store below +30°C.
solubility  Miscible with dichloromethane. Immiscible with hydrocarbons.
form  Liquid
color  Clear colorless to light brown
Water Solubility  reacts violently with water
Sensitive  Moisture Sensitive

Safety information for Trifluoromethanesulfonic anhydride

Signal word Danger
Pictogram(s)

Flame Over Circle
Oxidizers
GHS03

Corrosion
Corrosives
GHS05

Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H272:Oxidising liquids;Oxidising solids
H302:Acute toxicity,oral
H314:Skin corrosion/irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P220:Keep/Store away from clothing/…/combustible materials.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Trifluoromethanesulfonic anhydride

InChIKey WJKHJLXJJJATHN-UHFFFAOYSA-N

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