tert-Butylchlorodiphenylsilane
Synonym(s):tert-Butyldiphenylchlorosilane;TBDPSCl
- CAS NO.：58479-61-1
- Empirical Formula: C16H19ClSi
- Molecular Weight: 274.86
- MDL number: MFCD00000497
- EINECS: 261-282-0
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-05-15 13:45:27
What is tert-Butylchlorodiphenylsilane?
The Uses of tert-Butylchlorodiphenylsilane
Several newmethods have been developed
for using the reagent to protect primary and secondary alcohols
as their TBDPS ethers. In the presence of ammonium nitrate or
ammonium perchlorate, reaction between TBDPS-Cl and a primary
alcohol, such as benzyl alcohol, in DMF provided excellent
yields of the corresponding silyl ethers in just 15 min (eq 1).19
When silver nitrate was used as promoter, the reactions gave
inferior yields under otherwise identical conditions.
When TBDPS-Cl is used to react with hemiacetals, it converts
hemiacetals into ring-opened silyl ether carbonyl compounds, instead
of mixed acetals.Presumably, the sizable TBDPS group
presents too much steric hindrance for the formation of the corresponding
mixed silyl acetals.
What are the applications of Application
tert-Butyl(chloro)diphenylsilane is a silylating reagent
Properties of tert-Butylchlorodiphenylsilane
| Boiling point: | 90 °C0.01 mm Hg(lit.) |
| Density | 1.057 g/mL at 25 °C(lit.) |
| Flash point: | >230 °F |
| storage temp. | Inert atmosphere,2-8°C |
| solubility | miscible in most organic solvents. |
| form | Liquid |
| color | Clear colorless to yellow or slightly brown |
| Water Solubility | reacts |
| Sensitive | Moisture Sensitive |
Safety information for tert-Butylchlorodiphenylsilane
| Signal word | Danger |
| Pictogram(s) |
 Corrosion Corrosives GHS05  Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H314:Skin corrosion/irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for tert-Butylchlorodiphenylsilane
Abamectin manufacturer
JIVICHEM SYNTHESIS PVT LTD
1Y
Phone:+91-7028392790
Whatsapp: +91 7028392790
product: 58479-61-1 tert-Butylchlorodiphenylsilane 98%
JSK Chemicals
1Y
Phone:+91 9879767970;+919879767970
Whatsapp: +91 9879767970
product: 58479-61-1 99%
New Products
3-N-BOC-(S)-AMINO BUTYRONITRILE 4-Piperidinopiperidine 2-Methyl-4-nitrobenzoic acid 2-(4-bromophenyl)-2-methylpropanoic acid 4-Acetyl-2-methylbenzoicacid Acetyl-meldrum's acid Ethyl-4-Pyrazole carboxylate 2,6 Di acetylpyridine 2,6-Pyridinedimethanol 5,7-Dichloro-3H-Imidazo[4,5-B]Pyridine 5-Bromo-2-Methoxy-4-Methyl-3-Nitropyridine 2-Fluoro-5-Iodopyridine 2-Fluoro-5-Methylpyridine 2-Chloro-3-Bromo-5-Amiopyridine METHYL-4-(BUTYRYLAMINO)3-METHYL-5-NITROBENZOATE TRANS-CYCLOBUTANE-1,2- DICARBOXYLIC ACID 5-Nitro indazole R-(-)-5-(2-AMINO-PROPYL)-2-METHOXY-BENZENESULFONAMIDE 1,3-cyclohexanedione 4-Aminophenaethylalchol (S)-(+)-4-BENZYL-2-OXAZOLIDINONE 3-NITRO-5-ACETYL IMINODIBENZYL 4-FLUORO PHENYL MAGNESIUM BROMIDE 1.0 M IN THF 1-HYDROXY-4-METHYL6-(2,4,4-TRI METHYL PHENYL)-2-PYRIDONE MONO ETHANOL AMINE(PIROCTONE OLAMINE)Related products of tetrahydrofuran
You may like
-
58479-61-1 tert-Butylchlorodiphenylsilane 98%View Details
58479-61-1 -
58479-61-1 99%View Details
58479-61-1 -
2,3 Dichloro-4-Hydroxy Aniline 39183-17-0 99%View Details
39183-17-0 -
17673-56-2 99%View Details
17673-56-2 -
13463-67-7 Titanium Dioxide 99%View Details
13463-67-7 -
143-07-7 99%View Details
143-07-7 -
20776-67-4 99%View Details
20776-67-4 -
acid blue 113, acid navy blue , wool navy blue 0View Details
3351-05-1
Statement: All products displayed on this website are only used for non medical purposes such as industrial applications or scientific research, and cannot be used for clinical diagnosis or treatment of humans or animals. They are not medicinal or edible.