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HomeProduct name listHexanal

Hexanal

Synonym(s):Aldehyde C6;Caproaldehyde;Hexaldehyde, Caproaldehyde, Hexylaldehyde;Hexanal (stabilised);Hexyl aldehyde

  • CAS NO.:66-25-1
  • Empirical Formula: C6H12O
  • Molecular Weight: 100.16
  • MDL number: MFCD00007027
  • EINECS: 200-624-5
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-12-26 18:17:13
Hexanal Structural Picture

What is Hexanal?

Description

Hexanal has a characteristic fruity odor and taste (on dilution). May be prepared from the calcium salt of caproic acid and formic acid.

Description

Hexanal, once commonly called caproic aldehyde, is a six-carbon straight-chain aldehyde. It is a clear liquid with an atmospheric-pressure boiling point of 131 oC. P. Bagard published the first synthesis of hexanal in 1907. It is found in foods ranging from olive oil to pears to Hass avocados. Its fruity flavor makes it a useful additive in the flavor industry.
In 2014, Y. Takeuchi and co-workers at the University of Tokyo studied hexanal in another context: They discovered that it and its isomer 4-methylpentanal act as pheromones in rats. They found that exposing rats to these chemicals in combination causes the rodents to display increasingly anxious behavior. Neither compound alone produces similar results.
Stressed-out rats also release the aldehyde mixture. In so doing, they increase the anxiety levels of other rats.

The Uses of Hexanal

Hexanal is used in the flavor industry to prepare fruity flavors. It is utilized as a flavoring agent in the food industry. It is also used in Witting and aldol reactions.

Properties of Hexanal

Melting point: -56 °C
Boiling point: 130-131 °C(lit.)
Density  0.816 g/mL at 20 °C
Flash point: 90 °F
storage temp.  2-8°C
solubility  6g/l
form  Liquid
color  Clear colorless to slightly yellow
Odor Pungent.
Water Solubility  4.8 g/L (20 ºC)
Sensitive  Air Sensitive

Safety information for Hexanal

Signal word Warning
Pictogram(s)

Flame
Flammables
GHS02

Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H226:Flammable liquids
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233:Keep container tightly closed.
P240:Ground/bond container and receiving equipment.
P241:Use explosion-proof electrical/ventilating/lighting/…/equipment.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for Hexanal

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