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HomeProduct name list4,4'-Methylenedianiline

4,4'-Methylenedianiline

Synonym(s):4,4′-Methylenedianiline;DAPM;MDA

  • CAS NO.:101-77-9
  • Empirical Formula: C13H14N2
  • Molecular Weight: 198.26
  • MDL number: MFCD00007914
  • EINECS: 202-974-4
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-05-09 09:50:29
4,4'-Methylenedianiline Structural Picture

What is 4,4'-Methylenedianiline?

Description

4,4'-Methylenedianiline is an industrial chemical that is not known to occur naturally. It is also commonly known as diaminodiphenylmethane or MDA. It occurs as a colorless to pale yellow solid and has a faint odor. 4,4'-Methylenedianiline is used mainly for making polyurethane foams, which have a variety of uses, such as insulating materials in mailing containers. It is also used for making coating materials, glues, Spandex? fiber, dyes, and rubber. 4,4'-Methylenedianiline is also a by-product of azo dyes. It is also possibly formed by hydrolysis of diphenylmethane-4A'-diisocyanate.

The Uses of 4,4'-Methylenedianiline

4,4'-methylenedianiline be used as organic intermediates. Mainly used for the synthesis of polyimide and as curing agent of epoxy resin.

Properties of 4,4'-Methylenedianiline

Melting point: 89-91 °C(lit.)
Boiling point: 242 °C2 mm Hg(lit.)
Density  1.15
Flash point: 430 °F
solubility  water: soluble
form  neat
color  White to Light yellow
Water Solubility  Slightly soluble. <0.1 g/100 mL at 19 ºC

Safety information for 4,4'-Methylenedianiline

Signal word Danger
Pictogram(s)

Skull and Crossbones
Acute Toxicity
GHS06

Health Hazard
GHS08

Environment
GHS09
GHS Hazard Statements H301:Acute toxicity,oral
H317:Sensitisation, Skin
H341:Germ cell mutagenicity
H350:Carcinogenicity
H370:Specific target organ toxicity, single exposure
H373:Specific target organ toxicity, repeated exposure
H410:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P202:Do not handle until all safety precautions have been read and understood.
P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P273:Avoid release to the environment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310:IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+P352:IF ON SKIN: wash with plenty of soap and water.

Computed Descriptors for 4,4'-Methylenedianiline

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