Acute toxicity - Category 3, Oral
Skin irritation, Category 2
Eye irritation, Category 2
H301 Toxic if swallowed
H315 Causes skin irritation
H319 Causes serious eye irritation
P264 Wash ... thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P301+P316 IF SWALLOWED: Get emergency medical help immediately.
P321 Specific treatment (see ... on this label).
P330 Rinse mouth.
P302+P352 IF ON SKIN: Wash with plenty of water/...
P332+P317 If skin irritation occurs: Get medical help.
P362+P364 Take off contaminated clothing and wash it before reuse.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P405 Store locked up.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
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Fresh air, rest. Half-upright position. Refer for medical attention.
Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Rinse mouth. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Give one or two glasses of water to drink. Refer for medical attention .
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Use dry chemical, carbon dioxide or alcohol-resistant foam.
Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.
In case of fire in the surroundings, use appropriate extinguishing media. In case of fire: keep drums, etc., cool by spraying with water.
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into covered containers. Carefully collect remainder. Then store and dispose of according to local regulations.
Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
NO open flames. NO contact with hot surfaces. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Separated from acids and food and feedstuffs.
TLV: 2.5 mg/m3, as TWA; A4 (not classifiable as a human carcinogen); BEI issued.EU-OEL: (as F): 2,5 mg/m3 as TWA.MAK: (inhalable fraction, as F): 1 mg/m3; peak limitation category: II(4); skin absorption (H); pregnancy risk group: C
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Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear face shield or eye protection in combination with breathing protection if powder.
Protective gloves.
Use ventilation (not if powder), local exhaust or breathing protection.
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Solid.
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996 °C. Atm. press.:1 atm. Remarks:Assumed at 1 atm.
1 695 °C. Atm. press.:1 atm. Remarks:Assumed at one atmosphere.
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Not°Considered to be a fire hazard
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Miscible with water
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1.4 mm Hg ( 0 °C)
2.758 g/mL. Temperature:20 °C.;Ca. 2.76. Temperature:20 °C.
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Decomposes on contact with hot surfaces or flames. This produces toxic and corrosive fumes. Reacts with acids. This produces toxic and corrosive fumes.
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The substance is irritating to the eyes, skin and respiratory tract. Ingestion could cause hypocalcaemia and hypokalaemia. This may result in central nervous system disorders and cardiac disorders.
The substance may have effects on the bones and teeth. This may result in fluorosis.
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying or when dispersed, especially if powdered.
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The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: UN1690 (For reference only, please check.)
IMDG: UN1690 (For reference only, please check.)
IATA: UN1690 (For reference only, please check.)
ADR/RID: SODIUM FLUORIDE, SOLID (For reference only, please check.)
IMDG: SODIUM FLUORIDE, SOLID (For reference only, please check.)
IATA: SODIUM FLUORIDE, SOLID (For reference only, please check.)
ADR/RID: 6.1 (For reference only, please check.)
IMDG: 6.1 (For reference only, please check.)
IATA: 6.1 (For reference only, please check.)
ADR/RID: III (For reference only, please check.)
IMDG: III (For reference only, please check.)
IATA: III (For reference only, please check.)
ADR/RID: No
IMDG: No
IATA: No
no data available
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Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available.