Pyrophoric solids, Category 1
Substances and mixtures, which in contact with water, emit flammable gases, Category 1
Hazardous to the aquatic environment, short-term (Acute) - Category Acute 1
Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 1
H250 Catches fire spontaneously if exposed to air
H260 In contact with water releases flammable gases which may ignite spontaneously
H410 Very toxic to aquatic life with long lasting effects
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P222 Do not allow contact with air.
P233 Keep container tightly closed.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P223 Do not allow contact with water.
P231+P232 Handle and store contents under inert gas/....Protect from moisture.
P273 Avoid release to the environment.
P302+P335+P334 IF ON SKIN: Brush off loose particles from skin. Immerse in cool water [or wrap in wet bandages].
P370+P378 In case of fire: Use ... to extinguish.
P391 Collect spillage.
P402+P404 Store in a dry place. Store in a closed container.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
no data available
Fresh air, rest. Seek medical attention if you feel unwell. See Notes.
First rinse with plenty of water for at least 15 minutes, then remove contaminated clothes and rinse again.
Rinse with plenty of water (remove contact lenses if easily possible).
Rinse mouth. Refer for medical attention .
no data available
no data available
Use dry chemical, carbon dioxide or alcohol-resistant foam.
Highly flammable. May ignite spontaneously on contact with air. Many reactions may cause fire or explosion. Finely dispersed particles form explosive mixtures in air. Risk of fire and explosion on contact with water or incompatible substances. See Chemical Dangers.
Use special powder, dry sand. NO water. NO foam, carbon dioxide. NO other agents. In case of fire: keep drums, etc., cool by spraying with water. NO direct contact of the substance with water.
Remove all ignition sources. Consult an expert! Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Do NOT wash away into sewer. Sweep spilled substance into covered dry containers. Then store and dispose of according to local regulations.
Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
NO open flames, NO sparks and NO smoking. NO contact with oxidizing agents, acids, bases, water or incompatible substances. Closed system, ventilation, explosion-proof electrical equipment and lighting. Prevent build-up of electrostatic charges (e.g., by grounding). Prevent deposition of dust. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Fireproof. Well closed. Separated from incompatible materials and : see Chemical Dangers. Store in an area without drain or sewer access. Provision to contain effluent from fire extinguishing.
MAK: (as Zn, respirable fraction): 0.1 mg/m3; peak limitation category: I(4); (as Zn, inhalable fraction): 2 mg/m3; peak limitation category: I(1); pregnancy risk group: C; (DFG 2016)
no data available
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear safety spectacles.
Protective gloves.
Use local exhaust.
no data available
silver or blueish-white foil or powder
no data available
no data available
420°C
907°C(lit.)
no data available
no data available
-17°C
460°C
no data available
no data available
no data available
Solubility in water: reaction
no data available
1 mm Hg ( 487 °C)
7.133g/mLat 25°C(lit.)
no data available
no data available
no data available
no data available
Dust explosion possible if in powder or granular form, mixed with air. If dry, it can be charged electrostatically by swirling, pneumatic transport, pouring, etc.On combustion forms zinc oxide fumes. See Notes. The substance is a strong reducing agent. It reacts violently with oxidants, acids and bases. Reacts with water. This produces flammable/explosive gas (hydrogen - see ICSC 0001). Reacts violently with sulfur, halogenated hydrocarbons and many other substances. This generates fire and explosion hazard.
no data available
no data available
no data available
no data available
no data available
no data available
no data available
no data available
no data available
May cause mechanical irritation to the eyes and respiratory tract.
Repeated or prolonged contact with skin may cause dermatitis.
A nuisance-causing concentration of airborne particles can be reached quickly when dispersed.
no data available
no data available
no data available
no data available
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: UN1383 (For reference only, please check.)
IMDG: UN1383 (For reference only, please check.)
IATA: UN1383 (For reference only, please check.)
ADR/RID: PYROPHORIC METAL, N.O.S. or PYROPHORIC ALLOY, N.O.S. (For reference only, please check.)
IMDG: PYROPHORIC METAL, N.O.S. or PYROPHORIC ALLOY, N.O.S. (For reference only, please check.)
IATA: PYROPHORIC METAL, N.O.S. or PYROPHORIC ALLOY, N.O.S. (For reference only, please check.)
ADR/RID: 4.2 (For reference only, please check.)
IMDG: 4.2 (For reference only, please check.)
IATA: 4.2 (For reference only, please check.)
ADR/RID: I (For reference only, please check.)
IMDG: I (For reference only, please check.)
IATA: I (For reference only, please check.)
ADR/RID: Yes
IMDG: Yes
IATA: Yes
no data available
no data available
Zinc oxide fumes formed during combustion may cause metal fume fever (see ICSC 0208).Zinc may contain trace amounts of arsenic, when forming hydrogen, may also form toxic gas arsine (see ICSC0001 and ICSC0222).Zinc powder stabilized: Combustible solid, UN number: 3077, Hazard class: 9, Packing group: III; GHS: Warning, H400, H410.