Flammable gases, Category 1A, Flammable gas
Gases under pressure: Liquefied gas
Germ cell mutagenicity, Category 2
Carcinogenicity, Category 1B
Specific target organ toxicity – repeated exposure, Category 2
H220 Extremely flammable gas
H280 Contains gas under pressure; may explode if heated
H341 Suspected of causing genetic defects
H350 May cause cancer
H373 May cause damage to organs through prolonged or repeated exposure
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P203 Obtain, read and follow all safety instructions before use.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P381 In case of leakage, eliminate all ignition sources.
P318 IF exposed or concerned, get medical advice.
P319 Get medical help if you feel unwell.
P403 Store in a well-ventilated place.
P410+P403 Protect from sunlight. Store in a well-ventilated place.
P405 Store locked up.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
no data available
Fresh air, rest.
ON FROSTBITE: rinse with plenty of water, do NOT remove clothes.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
Inhalation of vapor causes slight intoxication, some shortness of breath. Liquid may cause frostbite of eyes or skin. (USCG, 1999)
Basic treatment: Establish a patent airway. Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary . Monitor for shock and treat if necessary . Anticipate seizures and treat if necessary . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with normal saline during transport . Do not use emetics. For ingestion, rinse mouth and administer 5 ml/kg up to 200 ml of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool. Administer activated charcoal . Cover skin burns with sterile dressings after decontamination . Halogenated aliphatic hydrocarbons and related compounds
If material on fire or involved in fire: Do not extinguish fire unless flow can be stopped. Use water in flooding quantities as fog. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible. Vinyl fluoride, stabilized
Special Hazards of Combustion Products: Toxic hydrogen fluoride gas is generated in a fire. Behavior in Fire: Vapor is heavier than air and may travel considerable distance to a source of ignition and flash back. Containers may explode. (USCG, 1999)
Shut off supply; if not possible and no risk to surroundings, let the fire burn itself out. In other cases extinguish with powder, carbon dioxide. In case of fire: keep cylinder cool by spraying with water.
Evacuate danger area! Consult an expert! Ventilation. NEVER direct water jet on liquid. Personal protection: self-contained breathing apparatus. Remove fumes with fine water spray. Do NOT wash away into sewer.
Evacuate danger area! Consult an expert! Ventilation. NEVER direct water jet on liquid. Personal protection: self-contained breathing apparatus.
PRECAUTIONS FOR "CARCINOGENS": A high-efficiency particulate arrestor (HEPA) or charcoal filters can be used to minimize amt of carcinogen in exhausted air ventilated safety cabinets, lab hoods, glove boxes or animal rooms ... Filter housing that is designed so that used filters can be transferred into plastic bag without contaminating maintenance staff is avail commercially. Filters should be placed in plastic bags immediately after removal ... The plastic bag should be sealed immediately ... The sealed bag should be labelled properly ... Waste liquids ... should be placed or collected in proper containers for disposal. The lid should be secured & the bottles properly labelled. Once filled, bottles should be placed in plastic bag, so that outer surface ... is not contaminated ... The plastic bag should also be sealed & labelled. ... Broken glassware ... should be decontaminated by solvent extraction, by chemical destruction, or in specially designed incinerators. Chemical Carcinogens
NO open flames, NO sparks and NO smoking. Closed system, ventilation, explosion-proof electrical equipment and lighting. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Fireproof. Separated from strong oxidants. Cool. Store only if stabilized.Fireproof. Separated from strong oxidants. Cool. Store only if stabilized.
TLV: 1 ppm as TWA; A2 (suspected human carcinogen)
no data available
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear safety goggles or eye protection in combination with breathing protection.
Cold-insulating gloves. Protective clothing.
Use ventilation, local exhaust or breathing protection.
no data available
Vinyl fluoride, stabilized is a colorless gas with a faint ethereal odor. Shipped as a confined liquid under its vapor pressure. Any leak can either be liquid or vapor. Contact with the liquid can cause frostbite. Easily ignited. Vapors are heavier than air. Can asphyxiate by the displacement of air. Under prolonged exposure to fire or intense heat the containers may rupture violently and rocket.
Colorless gas [Note: Shipped as a liquefied compressed gas].
Faint, ethereal odor.
-160.5°C
-72°C
Flammable Gas
Lower flammable limit: 2.6% by volume; Upper flammable limit: 21.7% by volume
Flammable gas
860° F (USCG, 1999)
no data available
no data available
3.2347E-04 pascal/seconds (liquid) @ boiling point
Insoluble (NIOSH, 2016)
log Kow = 1.19 /Estimated/
25.2 atm (NIOSH, 2016)
0.615 g/cm3
1.58 (Air= 1)
no data available
The substance may freely polymerize. Decomposes on heating and on burning. This produces toxic gases of hydrogen fluoride.
no data available
Ignites in presence of heat or source of ignition.The vapour is heavier than air and may travel along the ground; distant ignition possible.VINYL FLUORIDE is light sensitive, peroxidizable monomer may initiate exothermic polymerization of the bulk material [Handling Chemicals Safely 1980. p. 958]. Sensitive to many oxidants.
no data available
During ozonolysis of vinyl fluoride an explosive solid residue is produced, and the volatile ozonide, trapped at -63 deg C, may explode spontaneously or during removal by syringe.
When heated to decomposition it emits toxic fumes of /hydrogen fluoride/.
no data available
no data available
no data available
no data available
Evaluation: There is inadequate evidence in humans for the carcinogenicity of vinyl fluoride. There is sufficient evidence in experimental animals for the carcinogenicity of vinyl fluoride. Overall evaluation: Vinyl fluoride is probably carcinogenic to humans (Group 2A). In making the overall evaluation, the working group took into account the following evidence: Vinyl fluoride is closely related structurally to the known carcinogen, vinyl chloride. The two chemicals cause the same rare tumor (hepatic hemangiosarcoma) in experimental animals, which is also a tumor caused by vinyl chloride in humans.
no data available
The liquid may cause frostbite. The substance may cause effects on the central nervous system.
This substance is probably carcinogenic to humans.
A harmful concentration of this gas in the air will be reached very quickly on loss of containment.
no data available
An estimated BCF of 2 was calculated for vinyl fluoride(SRC), using an estimated log Kow of 1.19(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC), provided the compound is not altered physically or chemically once released into the environment.
Using a structure estimation method based on molecular connectivity indices(1), the Koc for vinyl fluoride can be estimated to be 24(SRC). According to a classification scheme(2), this estimated Koc value suggests that vinyl fluoride is expected to have very high mobility in soil.
no data available
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: UN1860 (For reference only, please check.)
IMDG: UN1860 (For reference only, please check.)
IATA: UN1860 (For reference only, please check.)
ADR/RID: VINYL FLUORIDE, STABILIZED (For reference only, please check.)
IMDG: VINYL FLUORIDE, STABILIZED (For reference only, please check.)
IATA: VINYL FLUORIDE, STABILIZED (For reference only, please check.)
ADR/RID: 2.1 (For reference only, please check.)
IMDG: 2.1 (For reference only, please check.)
IATA: 2.1 (For reference only, please check.)
ADR/RID: (For reference only, please check.)
IMDG: (For reference only, please check.)
IATA: (For reference only, please check.)
ADR/RID: No
IMDG: No
IATA: No
no data available
no data available
High concentrations in the air cause a deficiency of oxygen with the risk of unconsciousness or death.Check oxygen content before entering area.