Acute toxicity - Category 4, Oral
Skin corrosion, Sub-category 1B
Acute toxicity - Category 2, Inhalation
H302 Harmful if swallowed
H314 Causes severe skin burns and eye damage
H330 Fatal if inhaled
P264 Wash ... thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P271 Use only outdoors or in a well-ventilated area.
P284 [In case of inadequate ventilation] wear respiratory protection.
P301+P317 IF SWALLOWED: Get medical help.
P330 Rinse mouth.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P363 Wash contaminated clothing before reuse.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P316 Get emergency medical help immediately.
P321 Specific treatment (see ... on this label).
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P320 Specific treatment is urgent (see ... on this label).
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
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Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention.
Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Rinse mouth. Do NOT induce vomiting. Refer for medical attention . See Notes.
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Use dry chemical, carbon dioxide or alcohol-resistant foam.
Not combustible but forms flammable gas on contact with water or damp air. Risk of fire and explosion on contact with water or moisture.
Use powder, carbon dioxide. NO water. In case of fire: keep drums, etc., cool by spraying with water. NO direct contact with water. Combat fire from a sheltered position.
Evacuate danger area! Consult an expert! Personal protection: chemical protection suit including self-contained breathing apparatus. Ventilation. Do NOT let this chemical enter the environment. Do NOT wash away into sewer. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. NEVER direct water jet on liquid.
Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
NO open flames, NO sparks and NO smoking. NO contact with water or moisture. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Fireproof. Provision to contain effluent from fire extinguishing. Cool. Dry.
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Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear safety goggles, face shield or eye protection in combination with breathing protection.
Protective gloves. Protective clothing.
Use ventilation, local exhaust or breathing protection.
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clear, colorless liquid.
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-35°C
125°C(lit.)
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Solubility in water: reaction
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2.9 kPa(25°C)
1.668g/mLat 25°C(lit.)
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The vapour is heavier than air.Decomposes on heating and on contact with water and humidity. This produces toxic and corrosive fumes including phosphoric acid, hydrogen chloride and hydrogen sulfide. This generates fire and explosion hazard. Attacks many metals in the presence of water.
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The substance is corrosive to the eyes, skin and respiratory tract. The vapour is corrosive to the eyes, skin and respiratory tract. Corrosive on ingestion. Inhalation of the vapour may cause lung oedema. See Notes. If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis. Exposure could cause death. The effects may be delayed. Medical observation is indicated.
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A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20°C.
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The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: UN1837 (For reference only, please check.)
IMDG: UN1837 (For reference only, please check.)
IATA: UN1837 (For reference only, please check.)
ADR/RID: THIOPHOSPHORYL CHLORIDE (For reference only, please check.)
IMDG: THIOPHOSPHORYL CHLORIDE (For reference only, please check.)
IATA: THIOPHOSPHORYL CHLORIDE (For reference only, please check.)
ADR/RID: 8 (For reference only, please check.)
IMDG: 8 (For reference only, please check.)
IATA: 8 (For reference only, please check.)
ADR/RID: II (For reference only, please check.)
IMDG: II (For reference only, please check.)
IATA: II (For reference only, please check.)
ADR/RID: No
IMDG: No
IATA: No
no data available
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Reacts violently with fire extinguishing agents such as water, foam.The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort.Rest and medical observation is therefore essential.Immediate administration of an appropriate spray, by a doctor or a person authorized by him/her, should be considered.