Acute toxicity - Category 2, Oral
Acute toxicity - Category 1, Dermal
Hazardous to the aquatic environment, short-term (Acute) - Category Acute 1
H300 Fatal if swallowed
H310 Fatal in contact with skin
H400 Very toxic to aquatic life
P264 Wash ... thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P262 Do not get in eyes, on skin, or on clothing.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P273 Avoid release to the environment.
P301+P316 IF SWALLOWED: Get emergency medical help immediately.
P321 Specific treatment (see ... on this label).
P330 Rinse mouth.
P302+P352 IF ON SKIN: Wash with plenty of water/...
P316 Get emergency medical help immediately.
P361+P364 Take off immediately all contaminated clothing and wash it before reuse.
P391 Collect spillage.
P405 Store locked up.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
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Remove immediately from exposure. Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer immediately for medical attention. See Notes.
Remove contaminated clothes. Rinse and then wash skin with water and soap. See Notes. Refer immediately for medical attention.
Rinse with plenty of water for several minutes (remove contact lenses if easily possible). Refer immediately for medical attention.
Rinse mouth. Do NOT induce vomiting. See Notes. Give a slurry of activated charcoal in water to drink, but NOT if convulsions occur. Refer immediately for medical attention.
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Use dry chemical, carbon dioxide or alcohol-resistant foam.
Combustible. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire. Risk of fire and explosion if formulations contain flammable/explosive solvents.
Use water in large amounts, powder, alcohol-resistant foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.
Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable non-metallic containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.
Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
NO open flames. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Store only in original container. Separated from food and feedstuffs. Keep in a well-ventilated room. Dry. Store in an area without drain or sewer access. Provision to contain effluent from fire extinguishing.
TLV: (inhalable fraction): 0.01 mg/m3, as TWA; (skin); BEI issued.MAK: 0.060 mg/m3, 0.005 ppm; peak limitation category: II(2); skin absorption (H)
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Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear face shield or eye protection in combination with breathing protection.
Protective gloves. Protective clothing.
Use ventilation, local exhaust or breathing protection.
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COLOURLESS HYGROSCOPIC LIQUID.
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260.9°C at 760 mmHg
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>100°C
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Solubility in water: good
2.94
0.0193mmHg at 25°C
1.205 g/cm3
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Decomposes above 170°C . This produces flammable gas (ethylene) and toxic fumes including phosphorous oxides. Attacks some forms of plastic, rubber and coatings. The substance is corrosive to most metals.
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The substance is irritating to the eyes and skin. The substance may cause effects on the nervous system by a cholinesterase inhibiting effect. See Acute Hazards/Symptoms. This may result in convulsions, respiratory failure, heart failure and death. Medical observation is indicated.
Cholinesterase inhibition. Cumulative effects are possible. See Acute Hazards/Symptoms.
A harmful contamination of the air can be reached rather quickly on evaporation of this substance at 20°C , on spraying much faster.
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The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: UN2783 (For reference only, please check.)
IMDG: UN2783 (For reference only, please check.)
IATA: UN2783 (For reference only, please check.)
ADR/RID: ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC (For reference only, please check.)
IMDG: ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC (For reference only, please check.)
IATA: ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC (For reference only, please check.)
ADR/RID: 6.1 (For reference only, please check.)
IMDG: 6.1 (For reference only, please check.)
IATA: 6.1 (For reference only, please check.)
ADR/RID: I (For reference only, please check.)
IMDG: I (For reference only, please check.)
IATA: I (For reference only, please check.)
ADR/RID: Yes
IMDG: Yes
IATA: Yes
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Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available.Carrier solvents used in commercial formulations may change physical and toxicological properties.Isolate contaminated clothing by sealing in a bag or other container.Depending on the degree of exposure, periodic medical examination is suggested.Do NOT take working clothes home.