Corrosive to metals, Category 1
Acute toxicity - Category 3, Oral
Skin corrosion, Sub-category 1B
Serious eye damage, Category 1
Hazardous to the aquatic environment, short-term (Acute) - Category Acute 1
H290 May be corrosive to metals
H301 Toxic if swallowed
H314 Causes severe skin burns and eye damage
H400 Very toxic to aquatic life
P234 Keep only in original packaging.
P264 Wash ... thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P273 Avoid release to the environment.
P390 Absorb spillage to prevent material damage.
P301+P316 IF SWALLOWED: Get emergency medical help immediately.
P321 Specific treatment (see ... on this label).
P330 Rinse mouth.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P363 Wash contaminated clothing before reuse.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P316 Get emergency medical help immediately.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P317 Get medical help.
P391 Collect spillage.
P406 Store in a corrosion resistant/...container with a resistant inner liner.
P405 Store locked up.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
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Half-upright position. Artificial respiration may be needed. Refer immediately for medical attention.
Rinse skin with plenty of water or shower. Refer immediately for medical attention.
Rinse with plenty of water (remove contact lenses if easily possible). Refer immediately for medical attention.
Rinse mouth. Give one or two glasses of water to drink. Do NOT induce vomiting. Refer immediately for medical attention.
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Use dry chemical, carbon dioxide or alcohol-resistant foam.
Combustible. Gives off irritating or toxic fumes (or gases) in a fire.
Use water spray, foam, powder, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water. NO direct contact with water.
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance and filter respirator for inorganic gases and vapours adapted to the airborne concentration of the substance. Sweep spilled substance into covered plastic containers. Then store and dispose of according to local regulations.
Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
NO open flames. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Fireproof. Dry. Keep in a well-ventilated room. Separated from acids and strong oxidants.
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Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear safety goggles or eye protection in combination with breathing protection.
Protective gloves. Protective clothing.
Use local exhaust or breathing protection.
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Yellowish and crystal
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55°C
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90°C
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In water: 620 g/L (20 °C)
-3.5
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1,79 g/cm3
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The solution in water is a strong base. It reacts violently with acid and is corrosive. Decomposes on heating. This produces sulfur oxides. Decomposes on contact with water. This produces highly toxic and flammable hydrogen sulfide (see ICSC 0165). Attacks metal. Reacts with strong oxidants. This produces sulfur oxides.
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The substance is substance corrosive to the eyes, skin and respiratory tract. Inhalation may cause lung oedema. See Notes. Corrosive on ingestion. The substance hydrolyses rapidly on exposure to moisture releasing H2S. See ICSC 0165 .
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Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed.
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The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: UN2949 (For reference only, please check.)
IMDG: UN2949 (For reference only, please check.)
IATA: UN2949 (For reference only, please check.)
ADR/RID: SODIUM HYDROSULPHIDE, HYDRATED with not less than 25% water of crystallization (For reference only, please check.)
IMDG: SODIUM HYDROSULPHIDE, HYDRATED with not less than 25% water of crystallization (For reference only, please check.)
IATA: SODIUM HYDROSULPHIDE, HYDRATED with not less than 25% water of crystallization (For reference only, please check.)
ADR/RID: 8 (For reference only, please check.)
IMDG: 8 (For reference only, please check.)
IATA: 8 (For reference only, please check.)
ADR/RID: II (For reference only, please check.)
IMDG: II (For reference only, please check.)
IATA: II (For reference only, please check.)
ADR/RID: Yes
IMDG: Yes
IATA: Yes
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CAS No for sodium hydrogensulfide hydrate is 207683-19-0.UN 2318 refers to SODIUM HYDROSULFIDE with less than 25% water of crystallization; Hazard Class 4.2, Packing Group II.UN 2949 refers to SODIUM HYDROSULFIDE, hydrated with not less than 25% water of crystallization; Hazard Class 8 (corrosive), Packing Group IIImmediate administration of an appropriate inhalation therapy by a doctor, or by an authorized person, should be considered.