Acute toxicity - Category 4, Oral
H302 Harmful if swallowed
P264 Wash ... thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P301+P317 IF SWALLOWED: Get medical help.
P330 Rinse mouth.
none
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
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Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.
Rinse skin with plenty of water or shower.
Rinse with plenty of water for several minutes (remove contact lenses if easily possible).
Rinse mouth. Refer for medical attention .
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Use dry chemical, carbon dioxide or alcohol-resistant foam.
Not combustible. Gives off irritating or toxic fumes (or gases) in a fire. Risk of fire and explosion on contact with acids or oxidants.
In case of fire in the surroundings, use appropriate extinguishing media.
Personal protection: filter respirator for acid gases and vapours adapted to the airborne concentration of the substance. Collect leaking and spilled liquid in covered non-metallic containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Wash away remainder with plenty of water. Then store and dispose of according to local regulations.
Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
NO contact with acids or strong oxidizing agents. NO contact with incompatible materials: See Chemical Dangers Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Separated from acids, strong oxidants and food and feedstuffs. Well closed.
TLV: 5 mg/m3, as TWA; A4 (not classifiable as a human carcinogen)
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Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear safety spectacles.
Protective gloves.
Use ventilation.
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White crystals
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0 °C
104 °C
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515 g / L (20 °C, calcd)
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2.4 kPa(20°C)
Ca. 1.348 g/cm3. Temperature:20 °C.
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Decomposes on heating and on contact with acids. This produces sulfur oxides. Reacts with acids and strong oxidants. This generates fire hazard. The substance is a weak acid. Attacks metals.
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The substance is irritating to the skin, eyes, respiratory tract and gastrointestinal tract. Exposure could cause asthma-like reactions or urticaria in sensitive persons.
Repeated or prolonged inhalation may cause asthma-like symptoms. The substance may have effects on the skin.
No indication can be given about the rate at which a harmful concentration of this substance in the air is reached.
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The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: UN2693 (For reference only, please check.)
IMDG: UN2693 (For reference only, please check.)
IATA: UN2693 (For reference only, please check.)
ADR/RID: BISULPHITES, AQUEOUS SOLUTION, N.O.S. (For reference only, please check.)
IMDG: BISULPHITES, AQUEOUS SOLUTION, N.O.S. (For reference only, please check.)
IATA: BISULPHITES, AQUEOUS SOLUTION, N.O.S. (For reference only, please check.)
ADR/RID: 8 (For reference only, please check.)
IMDG: 8 (For reference only, please check.)
IATA: 8 (For reference only, please check.)
ADR/RID: III (For reference only, please check.)
IMDG: III (For reference only, please check.)
IATA: III (For reference only, please check.)
ADR/RID: No
IMDG: No
IATA: No
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