Chemical Book India PDF
Chemical Safety Data Sheet MSDS / SDS

Pentane SDS

Revision Date:2024-04-25 Revision Number:1
Section 1 Section 2 Section 3 Section 4 Section 5 Section 6 Section 7 Section 8 Section 9 Section 10 Section 11 Section 12 Section 13 Section 14 Section 15 Section 16

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product identifier

  • Product name: Pentane
  • CAS: 109-66-0

Relevant identified uses of the substance or mixture and uses advised against

  • Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
  • Uses advised against: none

Company Identification

  • Company:Chemicalbook.in
  • Address:5 vasavi Layout Basaveswara Nilayam Pragathi Nagar Hyderabad, India -500090
  • Telephone:+91 9550333722

SECTION 2: Hazards identification

Classification of the substance or mixture

Flammable liquids, Category 2

Aspiration hazard, Category 1

Specific target organ toxicity – single exposure, Category 3

Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 2

GHS label elements, including precautionary statements

  • Pictogram(s)
  • Signal word Danger
Hazard statement(s)

H225 Highly flammable liquid and vapour

H304 May be fatal if swallowed and enters airways

H336 May cause drowsiness or dizziness

H411 Toxic to aquatic life with long lasting effects

Precautionary statement(s)
Prevention

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P233 Keep container tightly closed.

P240 Ground and bond container and receiving equipment.

P241 Use explosion-proof [electrical/ventilating/lighting/...] equipment.

P242 Use non-sparking tools.

P243 Take action to prevent static discharges.

P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P271 Use only outdoors or in a well-ventilated area.

P273 Avoid release to the environment.

Response

P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse affected areas with water [or shower].

P370+P378 In case of fire: Use ... to extinguish.

P301+P316 IF SWALLOWED: Get emergency medical help immediately.

P331 Do NOT induce vomiting.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P319 Get medical help if you feel unwell.

P391 Collect spillage.

Storage

P403+P235 Store in a well-ventilated place. Keep cool.

P405 Store locked up.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

Disposal

P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

Other hazards which do not result in classification

no data available

SECTION 3: Composition/information on ingredients

Substance

  • Chemical name: Pentane
  • Common names and synonyms: Pentane
  • CAS number: 109-66-0
  • EC number: 203-692-4
  • Concentration: 100%

SECTION 4: First aid measures

Description of necessary first-aid measures

If inhaled

Fresh air, rest. Refer for medical attention.

Following skin contact

First rinse with plenty of water for at least 15 minutes, then remove contaminated clothes and rinse again.

Following eye contact

Rinse with plenty of water (remove contact lenses if easily possible).

Following ingestion

Rinse mouth. Do NOT induce vomiting. Refer immediately for medical attention.

Most important symptoms/effects, acute and delayed

Low toxicity. Very high vapor concentrations produce narcosis. Aspiration into lungs can produce chemical pneumonitis and/or pulmonary edema. (USCG, 1999)

Indication of immediate medical attention and special treatment needed, if necessary

Call for medical aid. Vapor, if inhaled, will cause dizziness or difficult breathing. Move to fresh air. If breathing has stopped, give artificial respiration. If breathing is difficult, give oxygen. Liquid is harmful if swallowed. ... Do not induce vomiting.

SECTION 5: Firefighting measures

Suitable extinguishing media

Use water spry, alcohol-resistant foam, dry chemical or carbon dioxide.

Specific hazards arising from the chemical

Behavior in Fire: Containers may explode (USCG, 1999)

Special protective actions for fire-fighters

Use powder, carbon dioxide, alcohol-resistant foam, water spray. In case of fire: keep drums, etc., cool by spraying with water.

SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures

Evacuate danger area! Consult an expert! Personal protection: filter respirator for organic gases and vapours of low boiling point adapted to the airborne concentration of the substance. Remove all ignition sources. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in dry sand or inert absorbent. Then store and dispose of according to local regulations. Do NOT wash away into sewer.

Environmental precautions

Evacuate danger area! Consult an expert! Personal protection: filter respirator for organic gases and vapours of low boiling point adapted to the airborne concentration of the substance. Remove all ignition sources. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in dry sand or inert absorbent. Then store and dispose of according to local regulations. Do NOT wash away into sewer.

Methods and materials for containment and cleaning up

Evacuate danger area! consult an expert! Personal protection: self-contained breathing apparatus. Ventilation. Remove all ignitino sources. Do NOT wash away into sewer. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in dry sand or inert absorbent...

SECTION 7: Handling and storage

Precautions for safe handling

NO open flames, NO sparks and NO smoking. NO contact with strong oxidizing agents. Closed system, ventilation, explosion-proof electrical equipment and lighting. Prevent build-up of electrostatic charges (e.g., by grounding). Do NOT use compressed air for filling, discharging, or handling. Use non-sparking handtools. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

Conditions for safe storage, including any incompatibilities

Fireproof. Separated from strong oxidants. Cool. Well closed. Store in an area without drain or sewer access. Provision to contain effluent from fire extinguishing.Storage temp: ambient. Venting: open (flame arrester) or pressure-vacuum.

SECTION 8: Exposure controls/personal protection

Control parameters

Occupational Exposure limit values

TLV: 1000 ppm as TWA.MAK: 3000 mg/m3, 1000 ppm; peak limitation category: II(2); pregnancy risk group: C.EU-OEL: 3000 mg/m3, 1000 ppm as TWA

Biological limit values

no data available

Appropriate engineering controls

Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.

Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Wear safety spectacles or eye protection in combination with breathing protection.

Skin protection

Protective gloves.

Respiratory protection

Use ventilation, local exhaust or breathing protection.

Thermal hazards

no data available

SECTION 9: Physical and chemical properties and safety characteristics

  • Physical state:

    N-pentane is a clear colorless liquid with a petroleum-like odor. Flash point 57°F. Boiling point 97°F. Less dense than water and insoluble in water. Hence floats on water. Vapors are heavier than air.

  • Colour:

    Colorless liquid [Note: A gas above 97 degrees F. May be utilized as a fuel].

  • Odour:

    Pleasant

  • Melting point/freezing point:

    304°C(lit.)

  • Boiling point or initial boiling point and boiling range:

    35-36°C(lit.)

  • Flammability:

    Class IA Flammable Liquid: Fl.P. below 73°F and BP below 100°F.

  • Lower and upper explosion limit/flammability limit:

    Lower flammable limit: 1.5% by volume; Upper flammable limit: 7.8% by volume.

  • Flash point:

    -49°C

  • Auto-ignition temperature:

    500°F

  • Decomposition temperature:

    no data available

  • pH:

    no data available

  • Kinematic viscosity:

    0.2224 mPa.sec at 25 deg C (liquid)

  • Solubility:

    less than 1 mg/mL at 70° F (NTP, 1992)

  • Partition coefficient n-octanol/water:

    log Kow = 3.39

  • Vapour pressure:

    527mmHg at 25°C

  • Density and/or relative density:

    0.626g/mLat 25°C(lit.)

  • Relative vapour density:

    2.48 (vs air)

  • Particle characteristics:

    no data available

SECTION 10: Stability and reactivity

Reactivity

1500 ppm (IDLH based on 10% of the lower explosion limit for safety considerations even though the relevant toxicological data indicated that irreversible health efects or impairment of escape existed only at higher concentrations.)

May explode on heating. Reacts with strong oxidants such as peroxides, nitrates and perchlorates. This generates fire and explosion hazard. Attacks some forms of plastic, rubber and coatings.

Chemical stability

no data available

Possibility of hazardous reactions

Flammable in the presence of a source of ignition when the temperature is above the flash point.The vapour is heavier than air and may travel along the ground; distant ignition possible. The vapour is heavier than air and may accumulate in lowered spaces causing a deficiency of oxygen.N-PENTANE is incompatible with strong oxidizers. It is also incompatible with strong acids, alkalis, and oxygen. Mixtures with chlorine gas have produced explosions. It will attack some forms of plastics, rubber, and coatings. (NTP, 1992).

Conditions to avoid

no data available

Incompatible materials

Strong oxidizers.

Hazardous decomposition products

When heated to decomposition it emits acrid smoke and irritating fumes.

SECTION 11: Toxicological information

Acute toxicity

  • Oral: no data available
  • Inhalation: LC50 Rat inhalation 364 g/cu m/4H
  • Dermal: no data available

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

no data available

Reproductive toxicity

no data available

STOT-single exposure

If swallowed the substance easily enters the airways and could result in aspiration pneumonitis. Inhalation of high concentrations of the vapour may cause depression of the central nervous system.

STOT-repeated exposure

The substance defats the skin, which may cause dryness or cracking.

Aspiration hazard

A harmful contamination of the air can be reached rather quickly on evaporation of this substance at 20°C.

SECTION 12: Ecological information

Toxicity

  • Toxicity to fish: no data available
  • Toxicity to daphnia and other aquatic invertebrates: EC50; Species: Daphnia magna (Water Flea) age 4-6 days, length 1.5 mm; Conditions: freshwater, static, 23 deg C, pH 6-7, dissolved oxygen 5-9 mg/L; Concentration: 135 mmol/cu m for 48 hr (95% confidence interval: 111-164 mmol/cu m); Effect: intoxication, immobilization /> or =97% purity
  • Toxicity to algae: no data available
  • Toxicity to microorganisms: no data available

Persistence and degradability

AEROBIC: n-Pentane reached 0.3, 3.2 and 10.1% of its theoretical BOD after 6, 24, and 72 hours, respectively, using a benzene-acclimated activated sludge(1). n-Pentane reached 0.7, 0.5 and 0.7% of its theoretical BOD at intervals of 6, 12, and 24 hours, respectively, using aeration units of sewage treatment facilities(2). Within 24 hours, pentane was oxidized to its corresponding methyl ketone, 2-pentanone(3,5), and the corresponding alcohol, 2-pentanol(4,5), by cell suspensions of over 20 methyltrophic organisms isolated from lake water and soil samples(3-5). n-Pentane, and 12 other components of gasoline were completely degraded using an activated sludge inoculum in less than 30 days(6). n-Pentane, present at 100 mg/L, reached 96% of its theoretical BOD in 4 weeks using an activated sludge inoculum at 30 mg/L in the Japanese MITI test(7). n-Pentane, present at 18.7 ug as a component in gasoline, was incubated in a New Jersey rainwater retention pond. The median half-life of total detectable gasoline hydrocarbons was 5.0 days(8).

Bioaccumulative potential

An estimated BCF of 80 was calculated for n-pentane(SRC), using a log Kow of 3.39(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is moderate(SRC).

Mobility in soil

Using a structure estimation method based on molecular connectivity indices(1), the Koc of n-pentane can be estimated to be 72(SRC). According to a classification scheme(2), this estimated Koc value suggests that n-pentane is expected to have high mobility in soil.

Other adverse effects

no data available

SECTION 13: Disposal considerations

Disposal methods

Product

The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

SECTION 14: Transport information

UN Number

ADR/RID: UN1265 (For reference only, please check.)

IMDG: UN1265 (For reference only, please check.)

IATA: UN1265 (For reference only, please check.)

UN Proper Shipping Name

ADR/RID: PENTANES, liquid (For reference only, please check.)

IMDG: PENTANES, liquid (For reference only, please check.)

IATA: PENTANES, liquid (For reference only, please check.)

Transport hazard class(es)

ADR/RID: 3 (For reference only, please check.)

IMDG: 3 (For reference only, please check.)

IATA: 3 (For reference only, please check.)

Packing group, if applicable

ADR/RID: I (For reference only, please check.)

IMDG: I (For reference only, please check.)

IATA: I (For reference only, please check.)

Environmental hazards

ADR/RID: Yes

IMDG: Yes

IATA: Yes

Special precautions for user

no data available

Transport in bulk according to IMO instruments

no data available

SECTION 15: Regulatory information

Safety, health and environmental regulations specific for the product in question

European Inventory of Existing Commercial Chemical Substances (EINECS)
Listed.
EC Inventory
Listed.
United States Toxic Substances Control Act (TSCA) Inventory
Listed.
China Catalog of Hazardous chemicals 2015
Listed.
New Zealand Inventory of Chemicals (NZIoC)
Listed.
(PICCS)
Listed.
Vietnam National Chemical Inventory
Listed.
IECSC)
Listed.
Korea Existing Chemicals List (KECL)
Listed.

SECTION 16: Other information

Abbreviations and acronyms

  • CAS: Chemical Abstracts Service
  • ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
  • RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
  • IMDG: International Maritime Dangerous Goods
  • IATA: International Air Transportation Association
  • TWA: Time Weighted Average
  • STEL: Short term exposure limit
  • LC50: Lethal Concentration 50%
  • LD50: Lethal Dose 50%
  • EC50: Effective Concentration 50%

References

  • IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
  • HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
  • IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
  • eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
  • CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
  • ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
  • ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
  • Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
  • ECHA - European Chemicals Agency, website: https://echa.europa.eu/

Other Information

High concentrations in the air cause a deficiency of oxygen with the risk of unconsciousness or death.Check oxygen content before entering the area.

Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. We as supplier shall not be held liable for any