Acute toxicity - Category 3, Oral
Skin corrosion, Sub-category 1B
Specific target organ toxicity – repeated exposure, Category 1
Hazardous to the aquatic environment, short-term (Acute) - Category Acute 1
Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 1
H301 Toxic if swallowed
H314 Causes severe skin burns and eye damage
H372 Causes damage to organs through prolonged or repeated exposure
H410 Very toxic to aquatic life with long lasting effects
P264 Wash ... thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P273 Avoid release to the environment.
P301+P316 IF SWALLOWED: Get emergency medical help immediately.
P321 Specific treatment (see ... on this label).
P330 Rinse mouth.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P363 Wash contaminated clothing before reuse.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P316 Get emergency medical help immediately.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P319 Get medical help if you feel unwell.
P391 Collect spillage.
P405 Store locked up.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
no data available
Fresh air, rest. Half-upright position. Refer immediately for medical attention.
Remove contaminated clothes. Rinse skin with plenty of water or shower for at least 15 minutes. Refer immediately for medical attention .
Rinse with plenty of water for several minutes (remove contact lenses if easily possible). Refer immediately for medical attention.
Rinse mouth. Do NOT induce vomiting. Refer immediately for medical attention.
Extremely toxic. The probable oral lethal dose for humans is 5-50 mg/kg, between 7 drops and 1 teaspoonful for a 70 kg (150 lb.) person. (EPA, 1998)
Although the use of BAL is indicated in severe inorganic mercury poisoning, the effectiveness of BAL in organic and elemental mercury poisoning is highly questionable. There are survivors of severe elemental mercury poisoning who have been treated only with supportive care. Dimercaprol is ineffective in reversing chronic organic neurologic effects but should be administered in acute ingestions of aryl organic mercury compounds (eg, phenylmercuric acetate, which is converted to inorganic mercury in the body).
If material is in solution with organic solvent, treat fire according to the solvent characteristics, in addition to the mercuric hazard. Unless otherwise indicated, use water spray, dry chemical, "alcohol resistant" foam, or carbon dioxide. Water may be ineffective.
Fire may produce irritating or poisonous gases. When heated to decomposition, very toxic mercuric fumes may be given off. Phenylmercuric ion is incompatible with halides, with which precipitates are formed. (EPA, 1998)
Use water spray, powder, foam, carbon dioxide.
Personal protection: chemical protection suit including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Sweep spilled substance into sealable containers. If appropriate, moisten first to prevent dusting. Then store and dispose of according to local regulations.
Personal protection: chemical protection suit including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Sweep spilled substance into sealable containers. If appropriate, moisten first to prevent dusting. Then store and dispose of according to local regulations.
Solid material: Control release and place material and disposal equipment into appropriate containers. Solvent-based material: Control runoff. In all cases, avoid contact with material. Keep material from entering the environment to the fullest extent practicable.
NO open flames, NO sparks and NO smoking. Closed system, dust explosion-proof electrical equipment and lighting. Prevent deposition of dust. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Fireproof. Provision to contain effluent from fire extinguishing. Separated from oxidants and food and feedstuffs. Cool. Dry. Well closed. Keep in a well-ventilated room. Store in an area without drain or sewer access.Store in a cool, dry, well-ventilated, noncombustible location. separate from oxidizing materials, halides.
TLV: 0.1 mg/m3, as TWA; (skin).MAK: skin absorption (H); sensitization of skin (SH); carcinogen category: 3B
no data available
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear face shield or eye protection in combination with breathing protection if powder.
Protective gloves. Protective clothing.
Use ventilation (not if powder), local exhaust or breathing protection.
no data available
Small lustrous prisms. Toxic by ingestion, inhalation and skin absorption. May severely irritate skin and eyes. Used as an herbicide and fungicide. as such, is mixed with organic solvent for the purpose of application.
WHITE TO CREAMY WHITE CRYSTALLINE POWDER OR SMALL WHITE PRISMS OR LEAFLETS
ODORLESS
149-153°C
no data available
Flammable. Gives off irritating or toxic fumes (or gases) in a fire.
no data available
140° F (USCG, 1999)
no data available
147-150°C
no data available
no data available
Slightly soluble (NTP, 1992)
log Kow= 0.71
9 mm Hg at 95° F (NTP, 1992)
2.4
(air = 1): 11.6
no data available
Decomposes on burning. This produces toxic vapours of mercury and mercury oxides. Reacts with oxidizing materials.
Stable for at least 2 years under normal storage conditions in unopened containers.
Combustible solid. If in solution, fire characteristics may depend on solvent.Dust explosion possible if in powder or granular form, mixed with air.PHENYLMERCURIC ACETATE may react with strong oxidizing agents (NTP, 1992).
no data available
no data available
Combustion by-products include mercuric vapors and fumes.
no data available
no data available
no data available
no data available
no data available
no data available
The substance is corrosive to the eyes, skin and respiratory tract. Corrosive on ingestion.
Repeated or prolonged contact may cause skin sensitization. The substance may have effects on the nervous system and kidneys. Animal tests show that this substance possibly causes toxicity to human reproduction or development.
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying.
Soil and aquatic microorganism: Phenlymercuric acetate is quickly degraded, with diphenylmercury as one of the major metabolic products.
Phenylmercuric acetate is not expected to bioconcentrate in aquatic organisms as it dissociates rapidly in water forming phenylmercuric cation. (SRC)
The Koc of phenylmercuric acetate is estimated as 60(SRC), using a log Kow of 0.71(1) and a regression-derived equation(2). According to a classification scheme(3), this estimated Koc value suggests that phenylmercuric acetate is expected to have a high mobility in soil. However, phenylmercuric acetate is expected to dissociate in moist soils to the cation(SRC). Cations generally adsorb to organic matter and clay more strongly than their neutral counterparts, suggesting that the mobility may be much lower in some soils(SRC). In a river study, it was found that the phenymercuric cation sorbed strongly to particles and humic material in the water column(4).
no data available
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: UN1674 (For reference only, please check.)
IMDG: UN1674 (For reference only, please check.)
IATA: UN1674 (For reference only, please check.)
ADR/RID: PHENYLMERCURIC ACETATE (For reference only, please check.)
IMDG: PHENYLMERCURIC ACETATE (For reference only, please check.)
IATA: PHENYLMERCURIC ACETATE (For reference only, please check.)
ADR/RID: 6.1 (For reference only, please check.)
IMDG: 6.1 (For reference only, please check.)
IATA: 6.1 (For reference only, please check.)
ADR/RID: II (For reference only, please check.)
IMDG: II (For reference only, please check.)
IATA: II (For reference only, please check.)
ADR/RID: Yes
IMDG: Yes
IATA: Yes
no data available
no data available
Explosive limits are unknown in literature, although the substance is combustible and has a flash point < 55°C.Do NOT take working clothes home.