Acute toxicity - Category 4, Oral
Acute toxicity - Category 4, Dermal
Acute toxicity - Category 4, Inhalation
Hazardous to the aquatic environment, short-term (Acute) - Category Acute 1
Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 1
H302 Harmful if swallowed
H312 Harmful in contact with skin
H332 Harmful if inhaled
H410 Very toxic to aquatic life with long lasting effects
P264 Wash ... thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P301+P317 IF SWALLOWED: Get medical help.
P330 Rinse mouth.
P302+P352 IF ON SKIN: Wash with plenty of water/...
P317 Get medical help.
P321 Specific treatment (see ... on this label).
P362+P364 Take off contaminated clothing and wash it before reuse.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P391 Collect spillage.
none
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
no data available
Fresh air, rest.
Remove contaminated clothes. Rinse and then wash skin with water and soap.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Rinse mouth.
Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: Inhalation of material may be harmful. Contact may cause burns to skin and eyes. Inhalation of Asbestos dust may have a damaging effect on the lungs. Fire may produce irritating, corrosive and/or toxic gases. Some liquids produce vapors that may cause dizziness or suffocation. Runoff from fire control may cause pollution. (ERG, 2016)
Emergency and supportive measures: Treat bronchospasm and anaphylaxis if they occur. Observe patients with a history of large ingestions for at least 4-6 hours for any signs of CNS depression or seizures. Pyrethrins and pyrethroids
Use carbon dioxide, foam, or dry chemical /on fires involving pyrethroids/. Pyrethrum
Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]: Some may burn but none ignite readily. Containers may explode when heated. Some may be transported hot. For UN3508, be aware of possible short circuiting as this product is transported in a charged state. (ERG, 2016)
Use powder, AFFF, foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.
Do NOT wash away into sewer. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.
Do NOT wash away into sewer. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.
SRP: Wastewater from contaminant suppression, cleaning of protective clothing/equipment, or contaminated sites should be contained and evaluated for subject chemical or decomposition product concentrations. Concentrations shall be lower than applicable environmental discharge or disposal criteria. Alternatively, pretreatment and/or discharge to a POTW is acceptable only after review by the governing authority. Due consideration shall be given to remediation worker exposure (inhalation, dermal and ingestion) as well as fate during treatment, transfer and disposal. If it is not practicable to manage the chemical in this fashion, it must meet Hazardous Material Criteria for disposal.
NO open flames. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. Keep in a well-ventilated room.Ventilate well. Store in closed drum in cool, dry place.
no data available
no data available
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear safety goggles.
Protective gloves.
Use ventilation, local exhaust or breathing protection.
no data available
Phenothrin is a pale yellow to yellow-brown liquid. Non corrosive. Used as an insecticide.
Colorless liquid
Faint characteristic odor
no data available
437°C at 760 mmHg
Combustible. Liquid formulations containing organic solvents may be flammable.
no data available
186.6°C
no data available
no data available
pH = 5.16 at 20 deg C
no data available
Soluble in xylene and acetone
log Kow = 7.54 (est)
0.009mmHg at 25°C
1.12 g/cm3
no data available
no data available
Insoluble in water. Hydrolyzed by alkalis.
Stable under irradiation, in most organic solvents, and on inorganic mineral diluents.
Combustible. Liquid formulations containing organic solvents may be flammable.A pyrethroid derivative.
no data available
Incompatible with alkaline materials.
When heated to decomposition it emits acrid smoke and fumes. (+)-cis,trans-Phenothrin
no data available
no data available
no data available
no data available
no data available
no data available
The substance is irritating to the eyes.
no data available
No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20°C.
AEROBIC: Although environmental biodegradation data specific to phenothrin were not available(SRC, 2009), the pyrethroid class of insecticides is readily degraded by environmental microorganisms(1,2). Residues of trans-phenothrin fell to <10 ppb (initial concentration not specified) within 45 days in an aerobic soil(2). Pyrethroids are metabolized by both hydrolytic and oxidative processes(2).
An estimated BCF of 230 was calculated for phenothrin(SRC), using a log Kow of 6.01(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is high, provide the compound is not metabolized by the organism(SRC).
The Koc of phenothrin is estimated as 1.2X10+5(SRC), using a log Kow of 6.01(1) and a regression-derived equation(2). According to a classification scheme(3), this estimated Koc value suggests that phenothrin is expected to be immobile in soil.
no data available
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: UN3082 (For reference only, please check.)
IMDG: UN3082 (For reference only, please check.)
IATA: UN3082 (For reference only, please check.)
ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (For reference only, please check.)
IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (For reference only, please check.)
IATA: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (For reference only, please check.)
ADR/RID: 9 (For reference only, please check.)
IMDG: 9 (For reference only, please check.)
IATA: 9 (For reference only, please check.)
ADR/RID: III (For reference only, please check.)
IMDG: III (For reference only, please check.)
IATA: III (For reference only, please check.)
ADR/RID: Yes
IMDG: Yes
IATA: Yes
no data available
no data available
Carrier solvents used in commercial formulations may change physical and toxicological properties.