Oxidizing liquids, Category 1
Skin corrosion, Sub-category 1A
H271 May cause fire or explosion; strong oxidizer
H314 Causes severe skin burns and eye damage
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P220 Keep away from clothing and other combustible materials.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P283 Wear fire resistant or flame retardant clothing.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash ... thoroughly after handling.
P306+P360 IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P371+P380+P375 In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
P370+P378 In case of fire: Use ... to extinguish.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P363 Wash contaminated clothing before reuse.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P316 Get emergency medical help immediately.
P321 Specific treatment (see ... on this label).
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P420 Store separately.
P405 Store locked up.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
no data available
Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention. See Notes.
Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Rinse mouth. Do NOT induce vomiting. Refer for medical attention .
Inhalation of vapors or mist causes burning sensation of nose and throat, and lung irritation with coughing; prolonged or excessive exposure could cause vomiting and severe coughing. Ingestion causes blistering and burns of mouth and stomach. Contact with eyes or skin causes blistering and burns. (USCG, 1999)
Excerpt from ERG Guide 140 [Oxidizers]: Inhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns or death. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may cause pollution. (ERG, 2016)
no data available
Combat fires from safe distance or protected location. flood discharge area with water. cool exposed containers with water. aqueous soln
Behavior in Fire: Above 160°C (320°F) will react with combustible material and increase intensity of fire. Containers may explode. (USCG, 1999)
Excerpt from ERG Guide 140 [Oxidizers]: These substances will accelerate burning when involved in a fire. Some may decompose explosively when heated or involved in a fire. May explode from heat or contamination. Some will react explosively with hydrocarbons (fuels). May ignite combustibles (wood, paper, oil, clothing, etc.). Containers may explode when heated. Runoff may create fire or explosion hazard. (ERG, 2016)
In case of fire in the surroundings: water in large amounts, water spray. In case of fire: keep drums, etc., cool by spraying with water. Combat fire from a sheltered position.
Evacuate danger area! Consult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT absorb in saw-dust or other combustible absorbents. Absorb liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Cautiously neutralize remainder. Do NOT wash away into sewer.
Evacuate danger area! Consult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT absorb in saw-dust or other combustible absorbents. Absorb liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Cautiously neutralize remainder. Do NOT wash away into sewer.
Neutralizing agents for acids & caustics: flush with water & rinse with dilute sodium bicarbonate or soda ash solution.
NO contact with combustible substances or reducing agents. Do NOT expose to friction or shock. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Fireproof. See Chemical Dangers. Well closed.REAGENT BOTTLE--MAX 1-LB, GLASS-STOPPERED, GLASS BOTTLE; KEPT IN A HEAVY GLASS TRAY WITH LARGER CAPACITY. ADDN LAB STORAGE SHOULD BE IN ORIGINAL BOTTLES INSIDE A GLASS CONTAINER PADDED WITH GLASS WOOL & HAVING GREATER CAPACITY THAN THE CONTAINER. CARBOYS & LARGE BOTTLES SHOULD BE STORED ON ACID-RESISTING NONCOMBUSTIBLE SHELVES, IN A NONCOMBUSTIBLE STRUCTURE. ALL STORAGE MUST BE SEPARATED FROM COMBUSTIBLE MATERIALS, ORG MATERIALS, STRONG DEHYDRATING AGENTS, OXIDIZING & REDUCING AGENTS. ...MUST BE STORED WHERE IT WILL NOT FREEZE... PROTECT AGAINST PHYSICAL DAMAGE. ELECTRICAL WIRING...IN STORAGE AREAS MUST BE OF WATERTIGHT TYPE TO PROTECT AGAINST CORROSIVE ACTION OF VAPORS.
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Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear face shield or eye protection in combination with breathing protection.
Protective gloves. Protective clothing.
Use ventilation, local exhaust or breathing protection. Use appropriate engineering controls.
no data available
Perchloric acid, with more than 50% but not more than 72% acid is a clear colorless odorless aqueous solution. Corrosive to metals and tissue. Closed containers may rupture violently under prolonged exposure to heat.
COLORLESS, OILY LIQUID
odorless
-112°C
39°C
Not combustible but enhances combustion of other substances. Many reactions may cause fire or explosion. Gives off irritating or toxic fumes (or gases) in a fire.
no data available
113°C
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19°C
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MISCIBLE IN COLD WATER
no data available
6.8 mm Hg ( 25 °C)
1.664g/mLat 25°C
~2.1 (vs air)
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May explode on heating. Decomposes on heating. This produces toxic and corrosive fumes. The substance is a strong oxidant. It reacts violently with combustible and reducing materials, organic materials and strong bases. This generates fire and explosion hazard. Attacks many metals. This produces flammable/explosive gas (hydrogen - see ICSC 0001). The acid is unstable if the concentration is over 72%; may explode by shock or concussion when dry or drying. Mixtures with combustible material (such as paper) may ignite spontaneously at room temperature.
VOLATILE
AQ ACID...MAY DEFLAGRATE IN CONTACT WITH OXIDIZABLE SUBSTANCES. /AQUEOUS SOLN/PERCHLORIC ACID, [> 50% BUT <= 72% STRENGTH] is a solution of a strong oxidizing acid. May react vigorously or deflagrate when mixed with oxidizable material [Merck]. This includes (but is not limited to) alcohols, amines, boranes, dicyanogen, hydrazines, hydrocarbons, hydrogen, nitroalkanes, powdered metals, silanes, or thiols [Bretherick 1979. p.174]. Perchloric acid ignites on contact with sulfinyl chloride. (Bailar, 1973, Vol. 2, 1442).
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Mixtures of.../acetic acid, perchloric acid and acetic anhydride/ have varying degrees of sensitivity to shock. ...addition of acetic anhydride to aq soln of perchloric acid causes formation of acetic acid which can react violently with perchloric acid.
Poisonous gases may be produced in fire. aqueous soln
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Corrosive. The vapour is very corrosive to the eyes, skin and respiratory tract. Inhalation of the vapour or mist may cause lung oedema. See Notes. The effects may be delayed. Medical observation is indicated.
no data available
No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20°C.
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The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: UN1873 (For reference only, please check.)
IMDG: UN1873 (For reference only, please check.)
IATA: UN1873 (For reference only, please check.)
ADR/RID: PERCHLORIC ACID with more than 50% but not more than 72% acid, by mass (For reference only, please check.)
IMDG: PERCHLORIC ACID with more than 50% but not more than 72% acid, by mass (For reference only, please check.)
IATA: PERCHLORIC ACID with more than 50% but not more than 72% acid, by mass (For reference only, please check.)
ADR/RID: 5.1 (For reference only, please check.)
IMDG: 5.1 (For reference only, please check.)
IATA: 5.1 (For reference only, please check.)
ADR/RID: I (For reference only, please check.)
IMDG: I (For reference only, please check.)
IATA: I (For reference only, please check.)
ADR/RID: No
IMDG: No
IATA: No
no data available
no data available
DO NOT use perchloric acid in a hood designed for other purposes.The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential.Immediate administration of an appropriate inhalation therapy by a doctor, or by an authorized person, should be considered.Rinse contaminated clothing with plenty of water because of fire hazard.NEVER pour water into this substance; when dissolving or diluting always add it slowly to the water.