Acute toxicity - Category 3, Dermal
Skin irritation, Category 2
Eye irritation, Category 2
Skin sensitization, Category 1
H311 Toxic in contact with skin
H315 Causes skin irritation
H319 Causes serious eye irritation
H317 May cause an allergic skin reaction
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P264 Wash ... thoroughly after handling.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P272 Contaminated work clothing should not be allowed out of the workplace.
P302+P352 IF ON SKIN: Wash with plenty of water/...
P316 Get emergency medical help immediately.
P321 Specific treatment (see ... on this label).
P361+P364 Take off immediately all contaminated clothing and wash it before reuse.
P332+P317 If skin irritation occurs: Get medical help.
P362+P364 Take off contaminated clothing and wash it before reuse.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P333+P317 If skin irritation or rash occurs: Get medical help.
P405 Store locked up.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
no data available
Fresh air, rest. Refer for medical attention.
Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention .
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Rinse mouth. Give one or two glasses of water to drink. Refer for medical attention .
no data available
Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR if necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on the left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. Poisons A and B
Use water spray, powder, alcohol-resistant foam, carbon dioxide.
Combustible.
Use water spray, powder, alcohol-resistant foam, carbon dioxide.
Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Personal protection: chemical protection suit.
Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Personal protection: chemical protection suit.
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
NO open flames. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Cool. Store only if stabilized.The effectiveness of phenolic inhibitors is dependent on the presence of oxygen and the monomers must be stored under air rather than an inert atmosphere. Temp must be kept low to minimize formation of peroxides and other products. ... The acrylic esters may be stored in mild or stainless steel, or aluminum. Acrylic acid & derivatives
no data available
no data available
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear safety spectacles, face shield or eye protection in combination with breathing protection.
Protective gloves. Protective clothing.
Use local exhaust or breathing protection.
no data available
LIQUID.
Colorless liquid
no data available
6°C(lit.)
96°C/0.8mmHg(lit.)
Combustible.
no data available
113°C
no data available
no data available
no data available
no data available
Solubility in water: poor
log Kow = 2.48 (est)
0.015mmHg at 25°C
1.031g/mLat 25°C(lit.)
7.3 (Air = 1)
no data available
The substance may polymerize.
no data available
Vapours are uninhibited and may polymerize in vents or flame arresters, causing blockage.
no data available
no data available
When heated to decomposition it emits acrid smoke and irritating fumes.
no data available
no data available
no data available
no data available
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no data available
The substance is irritating to the eyes, skin and respiratory tract.
Repeated or prolonged contact may cause skin sensitization.
No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20°C.
AEROBIC: Acrylates such as acrylate, butyl acrylate and hydroxypropyl acrylate have been shown to biodegrade readily in Japanese MITI tests(1); these acrylates, present at 100 mg/L, reached 52-61% of their theoretical BOD in 2 weeks (or 83% in 4 weeks) using an activated sludge inoculum at 30 mg/L in the Japanese MITI test(1). By analogy, 2,2-dimethyltrimethylene acrylate may also biodegrade readily(SRC).
An estimated BCF of 20 was calculated in fish for 2,2-dimethyltrimethylene acrylate(SRC), using an estimated log Kow of 2.48(1) and a regression-derived equation(1). According to a classification scheme(2), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC).
Using a structure estimation method based on molecular connectivity indices(1), the Koc of 2,2-dimethyltrimethylene acrylate can be estimated to be 40(SRC). According to a classification scheme(2), this estimated Koc value suggests that 2,2-dimethyltrimethylene acrylate is expected to have very high mobility in soil.
no data available
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: no data available
IMDG: no data available
IATA: no data available
ADR/RID: no data available
IMDG: no data available
IATA: no data available
ADR/RID: 6.1 (For reference only, please check.)
IMDG: 6.1 (For reference only, please check.)
IATA: 6.1 (For reference only, please check.)
ADR/RID: III (For reference only, please check.)
IMDG: III (For reference only, please check.)
IATA: III (For reference only, please check.)
ADR/RID: No
IMDG: No
IATA: No
no data available
no data available
An added stabilizer or inhibitor can influence the toxicological properties of this substance; consult an expert.