Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 2
H411 Toxic to aquatic life with long lasting effects
P273 Avoid release to the environment.
P391 Collect spillage.
none
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
no data available
Move the victim into fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration and consult a doctor immediately. Do not use mouth to mouth resuscitation if the victim ingested or inhaled the chemical.
Take off contaminated clothing immediately. Wash off with soap and plenty of water. Consult a doctor.
Rinse with pure water for at least 15 minutes. Consult a doctor.
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
ACUTE/CHRONIC HAZARDS: Toxic. May cause allergic reaction. (NTP, 1992)
Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR if necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on the left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. Poisons A and B
Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
no data available
Wear self-contained breathing apparatus for firefighting if necessary.
Avoid dust formation. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. Use personal protective equipment.Wear chemical impermeable gloves. Ensure adequate ventilation.Remove all sources of ignition. Evacuate personnel to safe areas.Keep people away from and upwind of spill/leak.
Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.
ACCIDENTAL RELEASE MEASURES: Personal precautions, protective equipment and emergency procedures: Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation.; Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.; Methods and materials for containment and cleaning up: Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal.
Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Conditions for safe storage, including any incompatibilities: Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.
no data available
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Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear tightly fitting safety goggles with side-shields conforming to EN 166(EU) or NIOSH (US).
Wear fire/flame resistant and impervious clothing. Handle with gloves. Gloves must be inspected prior to use. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
If the exposure limits are exceeded, irritation or other symptoms are experienced, use a full-face respirator.
no data available
Liquid. Oily.
Colourless.
Warm woody, dry, and fruity odor
-35 °C. Remarks:Other details not available.
263.8 °C. Atm. press.:966 hPa. Remarks:Other details not available.
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120.1 °C. Atm. press.:966 hPa.
Atm. press.:966 hPa. Remarks:4-(2,6,6-trimethylcyclohex-1-ene-1-yl)-but-3-ene-2-one did not catch fire on being exposed to air at room temperature of 27°C.
no data available
5.67. Remarks:Relatively Acidic.
kinematic viscosity (in mm2/s) = 16.869. Temperature:27.0°C.
Slightly soluble (NTP, 1992)
Pow = 80. Temperature:27 °C. Remarks:Log Pow = 1.903.
3.03 Pa. Temperature:25 °C.
0.852 g/cm3. Temperature:27 °C.
no data available
no data available
Slightly water soluble (NTP, 1992).
Stable under recommended storage conditions.
Combustible liquid.BETA-IONONE may react vigorously with oxidizing agents. May react exothermically with reducing agents to release hydrogen gas.
no data available
Incompatible materials: Strong oxidizing agents.
When heated to decomposition it emits acrid smoke and fumes.
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AEROBIC: Using the OECD 301F method (manometric respirometry) with an activated sludge inoculum, beta-ionone, at 50 mg/L, reached 79% of its theoretical BOD in 28 days which classified the compound as readily biodegradable(1). beta-Ionone was also classified as readily biodegradable by the results of a CO2-evolution test where beta-ionone, at 10 mg/L, achieved 46% and 73% CO2 evolution after 7 and 28 days respectively(1). Another respirometry study reported 80% biodegradation of beta-ionone at 100 mg/L(2). In a spiked river water die-away test using water from the Murrumbidgee River, beta-ionone, at 6.28 ug/L, was degraded about 95% after 20 hours of incubation(1). Results of a modified MITI test (OECD 301C) reported 50% degradation after 28 days (consistent with inherent biodegradability), but concentrations or inoculum were not reported(1).
An estimated BCF of 202 was calculated in fish for beta-ionone(SRC), using a log Kow of 4.0(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is high(SRC), provided the compound is not metabolized by the organism(SRC).
Using a structure estimation method based on molecular connectivity indices(1), the Koc of beta-ionone can be estimated to be 670(SRC). According to a classification scheme(2), this estimated Koc value suggests that beta-ionone is expected to have low mobility in soil.
no data available
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: Yes
IMDG: Yes
IATA: Yes
no data available
no data available