Skin irritation, Category 2
Skin sensitization, Category 1
Acute toxicity - Category 4, Inhalation
Specific target organ toxicity – single exposure, Category 3
Germ cell mutagenicity, Category 2
Carcinogenicity, Category 1B
Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 3
H315 Causes skin irritation
H317 May cause an allergic skin reaction
H332 Harmful if inhaled
H335 May cause respiratory irritation
H341 Suspected of causing genetic defects
H350 May cause cancer
H412 Harmful to aquatic life with long lasting effects
P264 Wash ... thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P272 Contaminated work clothing should not be allowed out of the workplace.
P271 Use only outdoors or in a well-ventilated area.
P203 Obtain, read and follow all safety instructions before use.
P273 Avoid release to the environment.
P302+P352 IF ON SKIN: Wash with plenty of water/...
P321 Specific treatment (see ... on this label).
P332+P317 If skin irritation occurs: Get medical help.
P362+P364 Take off contaminated clothing and wash it before reuse.
P333+P317 If skin irritation or rash occurs: Get medical help.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P317 Get medical help.
P319 Get medical help if you feel unwell.
P318 IF exposed or concerned, get medical advice.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P405 Store locked up.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
no data available
Fresh air, rest.
Remove contaminated clothes. Rinse and then wash skin with water and soap.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Rinse mouth.
Exposure Routes: inhalation, skin absorption, ingestion, skin and/or eye contact Symptoms: Irritation eyes, skin; upper respiratory system; skin sensitization; narcosis; possible hematopoietic, reproductive effects; [potential occupational carcinogen] Target Organs: Eyes, skin, central nervous system, hematopoietic system, reproductive system (NIOSH, 2016)
Phenyl glycidyl ether percutaneous absorption rates were 13.5 mg/sq cm/hr in rats & 4.2 mg/sq cm/hr for rabbits.
Dry chemical, carbon dioxide, or alcohol foam.
This chemical is probably combustible. (NTP, 1992)
Use water spray, foam, powder, carbon dioxide.
Personal protection: chemical protection suit including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in covered containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.
Personal protection: chemical protection suit including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in covered containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.
Do NOT let this chemical enter the environment. Collect leaking liquid in covered containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place.
NO open flames. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Store in an area without drain or sewer access. Separated from strong oxidants, strong bases, strong acids and amines. Cool. Keep in the dark.Store in an area without drain or sewer access. Seperated from strong oxidants, strong bases, strong acids and amines. Cool. Keep in the dark.
TLV: 0.1 ppm as TWA; (skin); (SEN); A3 (confirmed animal carcinogen with unknown relevance to humans).MAK: skin absorption (H); sensitization of skin (SH); carcinogen category: 2
no data available
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear safety goggles or eye protection in combination with breathing protection.
Protective gloves. Protective clothing.
Use ventilation, local exhaust or breathing protection.
no data available
Liquid.
Colorless.
no data available
3.5 °C.
245 °C.
Class IIIB Combustible Liquid: Fl.P. at or above 200°F.
Combustible
120 °C.
430 °C.
no data available
no data available
no data available
1 to 5 mg/mL at 64° F (NTP, 1992)
log Pow = 1.61. Temperature:25 °C.
0.013 hPa. Temperature:25 °C.
1.111. Temperature:21 °C.
5.2 (vs air)
no data available
100 ppm; NIOSH considers phenyl glycidyl ether to be a potential occupational carcinogen.
The substance can presumably form explosive peroxides. The substance polymerizes under the influence of acids, bases and amines. Reacts violently with strong oxidants. This generates fire and explosion hazard.
no data available
PHENYL GLYCIDYL ETHER, an ether, can act as a base. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.
no data available
Incompatibilities: Contact with strong oxidizing agents may cause fires and explosions. Contact with amines, strong acids, and strong bases may cause polymerization with the liberation of heat and spattering. Exposure to light and air may result in the formation of explosive peroxides.
Energy of decomposition (in range 360-450 deg C) measured as 0.626 kJ/g.
no data available
no data available
no data available
no data available
Evaluation: No epidemiological data relevant to the carcinogenicity of phenyl glycidyl ether were available. There is sufficient evidence in experimental animals for the carcinogenicity of phenyl glycidyl ether. Overall evaluation: Phenyl glycidyl ether is possibly carcinogenic to humans (Group 2B).
no data available
The substance is irritating to the eyes, skin and respiratory tract.
Repeated or prolonged contact may cause skin sensitization. This substance is possibly carcinogenic to humans.
A harmful contamination of the air will be reached rather slowly on evaporation of this substance at 20°C; on spraying or dispersing, however, much faster.
AEROBIC: A 5-day theoretical BOD of 6% was measured for phenyl glycidyl ether using a standard dilution method and an effluent from a biological sanitary waste treatment plant as the inoculum(1). A 5-day theoretical BOD of 0% was measured using a BOD dilution method and an acclimated sewage inoculum(2). Phenyl glycidyl ether, present at 100 mg/L, reached 33% of its theoretical BOD in 4 weeks using an activated sludge inoculum at 30 mg/L and the Japanese MITI test(3).
An estimated BCF of 8 was calculated for phenyl glycidyl ether(SRC), using a water solubility of 2,400 mg/L(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC).
The Koc of phenyl glycidyl ether is estimated as 60(SRC), using a water solubility of 2,400 mg/L(1) and a regression-derived equation(2). According to a classification scheme(3), this estimated Koc value suggests that phenyl glycidyl ether is expected to have high mobility in soil.
no data available
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: No
IMDG: No
IATA: No
no data available
no data available
Do NOT take working clothes home.Check for peroxides prior to distillation; eliminate if found.