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Fresh air, rest. Refer for medical attention.
Remove contaminated clothes. Rinse and then wash skin with water and soap.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Rinse mouth. Refer for medical attention .
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Use dry chemical, carbon dioxide or alcohol-resistant foam.
Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.
In case of fire in the surroundings, use appropriate extinguishing media.
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Vacuum with specialist equipment (See Notes) or carefully sweep into containers. Carefully collect remainder. Then store and dispose of according to local regulations.
Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Separated from food and feedstuffs. Provision to contain effluent from fire extinguishing.
TLV: (as As): 0.01 mg/m3, as TWA; A1 (confirmed human carcinogen); BEI issued.MAK: (as As): skin absorption (H); carcinogen category: 1; germ cell mutagen group: 3A
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Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear safety goggles or eye protection in combination with breathing protection if powder.
Protective gloves. Protective clothing.
Use closed system, ventilation or breathing protection.
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BROWN POWDER.
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No data.Decomposes on heating and on burning. This produces toxic fumes of arsenic and iron.
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The substance is irritating to the eyes, skin and respiratory tract. The substance may cause effects on the gastrointestinal tract, liver, skin and nervous system. This may result in severe gastroenteritis, degenerative liver damage, dermatitis, kidney impairment and neuropathy. The effects may be delayed. Medical observation is indicated.
Repeated or prolonged contact with skin may cause dermatitis, grey skin and hyperkeratosis. The substance may have effects on the nervous system, liver, cardiovascular system and respiratory tract. This may result in neuropathy, degenerative liver damage and skin lesions. This substance is carcinogenic to humans.
A harmful concentration of airborne particles can be reached quickly when dispersed, especially if powdered.
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The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: UN1607 (For reference only, please check.)
IMDG: UN1607 (For reference only, please check.)
IATA: UN1607 (For reference only, please check.)
ADR/RID: FERRIC ARSENITE (For reference only, please check.)
IMDG: FERRIC ARSENITE (For reference only, please check.)
IATA: FERRIC ARSENITE (For reference only, please check.)
ADR/RID: 6.1 (For reference only, please check.)
IMDG: 6.1 (For reference only, please check.)
IATA: 6.1 (For reference only, please check.)
ADR/RID: II (For reference only, please check.)
IMDG: II (For reference only, please check.)
IATA: II (For reference only, please check.)
ADR/RID: No
IMDG: No
IATA: No
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NEVER use a domestic-type vacuum cleaner to vacuum the substance, only use specialist equipment.Do NOT take working clothes home.Depending on the degree of exposure, periodic medical examination is suggested.The symptoms of poisoning do not become manifest until 0.5 to several hours.See ICSC 0013 and ICSC 0378.