Acute toxicity - Category 4, Dermal
Hazardous to the aquatic environment, short-term (Acute) - Category Acute 1
H312 Harmful in contact with skin
H400 Very toxic to aquatic life
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P273 Avoid release to the environment.
P302+P352 IF ON SKIN: Wash with plenty of water/...
P317 Get medical help.
P321 Specific treatment (see ... on this label).
P362+P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage.
none
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
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Move the victim into fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration and consult a doctor immediately. Do not use mouth to mouth resuscitation if the victim ingested or inhaled the chemical.
Take off contaminated clothing immediately. Wash off with soap and plenty of water. Consult a doctor.
Rinse with pure water for at least 15 minutes. Consult a doctor.
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
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Skin decontamination. Skin contamination should be treated promptly by washing with soap and water. Contamination of the eyes should be treated immediately by prolonged flushing of the eyes with large amounts of clean water. If dermal or ocular irritation persists, medical attention should be obtained without delay. Other herbicides
Use dry chemical, carbon dioxide or alcohol-resistant foam.
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Wear self-contained breathing apparatus for firefighting if necessary.
Avoid dust formation. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. Use personal protective equipment.Wear chemical impermeable gloves. Ensure adequate ventilation.Remove all sources of ignition. Evacuate personnel to safe areas.Keep people away from and upwind of spill/leak.
Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Store in temperatures above 4.4 deg C.
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Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear tightly fitting safety goggles with side-shields conforming to EN 166(EU) or NIOSH (US).
Wear fire/flame resistant and impervious clothing. Handle with gloves. Gloves must be inspected prior to use. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
If the exposure limits are exceeded, irritation or other symptoms are experienced, use a full-face respirator.
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Yellow crystals.
Yellow crystals
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98-99°C
409.1°C at 760mmHg
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201.2°C
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In acetone 1040, chloroform 670, benzene 473, xylene 227, ethanol 107, hexane 14 (all in g/L at 20 deg C).
log Kow = 4.30
3.6X10-6 mm Hg at 25 deg C
1.465g/cm3
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Relatively stable at room temperature; decomposes above 200 deg C. Dilute solutions are degraded by UV irradiation.
The emulsifiable concentrate is combustible.
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AEROBIC: Degradation of dinitroaniline herbicides in soil (including dinitramine) appears to be primarily by soil micro-organisms (1,2); little or no degradation of dinitroaniline herbicides has been reported for sterilized soils via autoclaving or potassium azide treatment(2). Aerobic degradation of dinitramine proceeds through a dealkylation step followed by progressive reduction of the nitro groups (2-4); cyclization of a reduced nitro group (an amino group) with alkyl groups forms benzimidazoles(2,4). Degradation is reported to be faster under moist soil conditions compared to dry conditions and faster at higher temperatures than lower temperatures(1,2).
An estimated BCF of 408 was calculated in fish for dinitramine(SRC), using an experimental log Kow of 4.30(1) and a regression-derived equation(2). An aquatic ecosystem study using Gambusia fish and a 3-day exposure period in the dark, determined a dinitramine BCF value of 235(3); the BCF value under sunlight conditions was 83; the lower BCF value in sunlight was thought to be the result of dinitramine photodegradation in sunlight. According to a classification scheme(4), BCF values of 235 and 408 suggest the potential for bioconcentration in aquatic organisms is high(SRC), provided the compound is not metabolized by the organism(SRC).
Based upon a variety of measured Koc values in different soils (range of 115 to 34,400), dinitramine has a recommended Koc of 4000(1). According to a classification scheme(2), this Koc value suggests that dinitramine is expected to have slight mobility in soil. In adsorption studies using a Plano silt loam soil(3), dinitramine did not leach more than 4 mm over a 17-day observation period. No leaching was detected for dinitramine or six other dinitroaniline herbicides during a 1-year period in which 145 cm of rainfall and irrigation water entered sandy loam plots(4); these dinitroaniline herbicides were essentially immobile in soil(4). Dinitramine is reported to be strongly adsorbed on soil with no leaching(5).
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The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: UN3077 (For reference only, please check.)
IMDG: UN3077 (For reference only, please check.)
IATA: UN3077 (For reference only, please check.)
ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (For reference only, please check.)
IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (For reference only, please check.)
IATA: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (For reference only, please check.)
ADR/RID: 9 (For reference only, please check.)
IMDG: 9 (For reference only, please check.)
IATA: 9 (For reference only, please check.)
ADR/RID: III (For reference only, please check.)
IMDG: III (For reference only, please check.)
IATA: III (For reference only, please check.)
ADR/RID: Yes
IMDG: Yes
IATA: Yes
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