Bisisopropyl peroxydicarbonate SDS
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Product identifier
- Product name： Bisisopropyl peroxydicarbonate
- CAS： 105-64-6
Relevant identified uses of the substance or mixture and uses advised against
- Relevant identified uses： For R&D use only. Not for medicinal, household or other use.
- Uses advised against： none
Company Identification
- Company：Chemicalbook.in
- Address：5 vasavi Layout Basaveswara Nilayam Pragathi Nagar Hyderabad, India -500090
- Telephone：+91 9550333722
SECTION 2: Hazards identification
Classification of the substance or mixture
Organic peroxides, Type B
Skin irritation, Category 2
Serious eye damage, Category 1
GHS label elements, including precautionary statements
-
Pictogram(s)
- Signal word Danger
H241 Heating may cause a fire or explosion
H315 Causes skin irritation
H318 Causes serious eye damage
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P234 Keep only in original packaging.
P235 Keep cool.
P240 Ground and bond container and receiving equipment.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P264 Wash ... thoroughly after handling.
P302+P352 IF ON SKIN: Wash with plenty of water/...
P321 Specific treatment (see ... on this label).
P332+P317 If skin irritation occurs: Get medical help.
P362+P364 Take off contaminated clothing and wash it before reuse.
P305+P354+P338 IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P317 Get medical help.
P403 Store in a well-ventilated place.
P410 Protect from sunlight.
P411 Store at temperatures not exceeding …°C/…°F.
P420 Store separately.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
Other hazards which do not result in classification
no data available
SECTION 3: Composition/information on ingredients
Substance
- Chemical name: Bisisopropyl peroxydicarbonate
- Common names and synonyms: Bisisopropyl peroxydicarbonate
- CAS number: 105-64-6
- EC number: 203-317-4
- Concentration: 100%
SECTION 4: First aid measures
Description of necessary first-aid measures
Move the victim into fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration and consult a doctor immediately. Do not use mouth to mouth resuscitation if the victim ingested or inhaled the chemical.
Take off contaminated clothing immediately. Wash off with soap and plenty of water. Consult a doctor.
Rinse with pure water for at least 15 minutes. Consult a doctor.
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
Most important symptoms/effects, acute and delayed
Inhalation overexposure unlikely, but prolonged exposure may cause lung edema. Contact with eyes may cause irritation. Solutions are severe primary skin irritants. (USCG, 1999)
Indication of immediate medical attention and special treatment needed, if necessary
Should be washed promptly from the skin to prevent irritation. Peroxides, org
SECTION 5: Firefighting measures
Suitable extinguishing media
Fight fires from explosion-resistant location. in advanced or massive fires, area should be evacuated. ... it is essential to maintain proper temp control of refrigeration system as material will decomp @ 53 deg f to release flammable products which must be properly vented. clean-up & salvage operations should not be attempted until deep-freeze unit has cooled completely. due caution should be exercised because of possibility of adverse contamination and chem change after heat exposure.
Specific hazards arising from the chemical
Special Hazards of Combustion Products: Flammable and/or toxic gases formed in fires include acetone, isopropyl alcohol, acetaldehyde, and ethane. Behavior in Fire: Undergoes auto- accelerative decomposition and may self-ignite. Confinement may lead to detonation. Fires very difficult to extinguish because air not needed (USCG, 1999)
Special protective actions for fire-fighters
Wear self-contained breathing apparatus for firefighting if necessary.
SECTION 6: Accidental release measures
Personal precautions, protective equipment and emergency procedures
Avoid dust formation. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. Use personal protective equipment.Wear chemical impermeable gloves. Ensure adequate ventilation.Remove all sources of ignition. Evacuate personnel to safe areas.Keep people away from and upwind of spill/leak.
Environmental precautions
Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.
Methods and materials for containment and cleaning up
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
SECTION 7: Handling and storage
Precautions for safe handling
Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Conditions for safe storage, including any incompatibilities
Should be stored in deep-freeze...unit in well-ventilated, unheated, well-detached, noncombustible building...must be stored @ low temp (below 0 deg f). refrigerated product should be placed in deep-freeze box with free-opening cover in...building. refrigerating unit & all electrical equip should be outside... alarm system.../needed/ to indicate any abnormal temp...within deep-freeze box. protect against physical damage. do not open containers in storage building.
SECTION 8: Exposure controls/personal protection
Control parameters
no data available
no data available
Appropriate engineering controls
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Individual protection measures, such as personal protective equipment (PPE)
Wear tightly fitting safety goggles with side-shields conforming to EN 166(EU) or NIOSH (US).
Wear fire/flame resistant and impervious clothing. Handle with gloves. Gloves must be inspected prior to use. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
If the exposure limits are exceeded, irritation or other symptoms are experienced, use a full-face respirator.
no data available
SECTION 9: Physical and chemical properties and safety characteristics
-
Physical state：
Diisopropyl peroxydicarbonate is a white solid (shipped packed in Dry Ice to stabilize) with a sharp unpleasant odor. Insoluble in sater and sinks in water. Used as polymerization catalyst. (USCG, 1999)
-
Colour：
Crystalline solid
-
Odour：
no data available
-
Melting point/freezing point：
12°C
-
Boiling point or initial boiling point and boiling range：
208°C at 760 mmHg
-
Flammability：
no data available
-
Lower and upper explosion limit/flammability limit：
no data available
-
Flash point：
79.1°C
-
Auto-ignition temperature：
no data available
-
Decomposition temperature：
no data available
-
pH：
no data available
-
Kinematic viscosity：
no data available
-
Solubility：
Almost insol in water; miscible with aliphatic and aromatic hydrocarbons, esters, ethers and chlorinated hydrocarbons
-
Partition coefficient n-octanol/water：
no data available
-
Vapour pressure：
3.373mmHg at 25°C
-
Density and/or relative density：
1.138 g/cm3
-
Relative vapour density：
no data available
-
Particle characteristics：
no data available
SECTION 10: Stability and reactivity
Reactivity
Highly flammable. Insoluble in water. Spontaneous decomposition at room temperature releases flammable toxic products.
Chemical stability
no data available
Possibility of hazardous reactions
REACTIVE, OXIDIZING, COMBUSTIBLE CMPD. ... SHOCK & HEAT SENSITIVE. DANGEROUS WHEN EXPOSED TO HEAT & FLAME. SPONTANEOUS CHEM REACTION, IGNITION...MAY OCCUR IF MIXED WITH READILY OXIDIZABLE, ORG OR FLAMMABLE MATERIALS OR CHEM ACCELERATORS.ISOPROPYL PEROXYDICARBONATE decomposes violently or explosively at temperatures 0-10°C owing to self- accelerating exothermic decomposition; Several explosions were due to shock, heat, or friction; amines and certain metals can cause accelerated decomposition [Bretherick 1979 p. 156]. Spontaneous decomposition possible at room temperature to release flammable and corrosive products (presence of stabilizer reduces this possibility). A strong oxidizing agent. May ignite organic compounds on contact, hence a fire risk. Strongly reduced material such as sulfides, nitrides, and hydrides can react explosively. Reacts at least to produce heat when mixed with members of most chemical classes. These reactions often generate gases (toxic and nontoxic). Subject to decomposition, buildup of heat and even an explosion if contaminated with a catalyst (often a transition metal such as cobalt, iron, manganese, nickel, or vanadium or a salt of a transition metal).
Conditions to avoid
no data available
Incompatible materials
Explodes on contact with amines or potassium iodide. May explode on contact with organic matter.
Hazardous decomposition products
Spontaneous decomposition at room temperature releases flammable and corrosive products.
SECTION 11: Toxicological information
Acute toxicity
- Oral: LD50 Rat oral 2140 mg/kg
- Inhalation: no data available
- Dermal: no data available
Skin corrosion/irritation
no data available
Serious eye damage/irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
no data available
Reproductive toxicity
no data available
STOT-single exposure
no data available
STOT-repeated exposure
no data available
Aspiration hazard
no data available
SECTION 12: Ecological information
Toxicity
- Toxicity to fish: no data available
- Toxicity to daphnia and other aquatic invertebrates: no data available
- Toxicity to algae: no data available
- Toxicity to microorganisms: no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Other adverse effects
no data available
SECTION 13: Disposal considerations
Disposal methods
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
SECTION 14: Transport information
UN Number
ADR/RID: UN3112 (For reference only, please check.)
IMDG: UN3112 (For reference only, please check.)
IATA: UN3112 (For reference only, please check.)
UN Proper Shipping Name
ADR/RID: ORGANIC PEROXIDE TYPE B, SOLID, TEMPERATURE CONTROLLED (For reference only, please check.)
IMDG: ORGANIC PEROXIDE TYPE B, SOLID, TEMPERATURE CONTROLLED (For reference only, please check.)
IATA: ORGANIC PEROXIDE TYPE B, SOLID, TEMPERATURE CONTROLLED (For reference only, please check.)
Transport hazard class(es)
ADR/RID: 5.2 (For reference only, please check.)
IMDG: 5.2 (For reference only, please check.)
IATA: 5.2 (For reference only, please check.)
Packing group, if applicable
ADR/RID: (For reference only, please check.)
IMDG: (For reference only, please check.)
IATA: (For reference only, please check.)
Environmental hazards
ADR/RID: No
IMDG: No
IATA: No
Special precautions for user
no data available
Transport in bulk according to IMO instruments
no data available
SECTION 15: Regulatory information
Safety, health and environmental regulations specific for the product in question
SECTION 16: Other information
Abbreviations and acronyms
- CAS: Chemical Abstracts Service
- ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
- RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
- IMDG: International Maritime Dangerous Goods
- IATA: International Air Transportation Association
- TWA: Time Weighted Average
- STEL: Short term exposure limit
- LC50: Lethal Concentration 50%
- LD50: Lethal Dose 50%
- EC50: Effective Concentration 50%
References
- IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
- HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
- IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
- eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
- CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
- ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
- ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
- Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
- ECHA - European Chemicals Agency, website: https://echa.europa.eu/