Eye irritation, Category 2
H319 Causes serious eye irritation
P264 Wash ... thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
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none
no data available
Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention.
First rinse with plenty of water for at least 15 minutes, then remove contaminated clothes and rinse again. Refer for medical attention .
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Rinse mouth. Do NOT induce vomiting. Refer for medical attention .
Vapor concentrations too low to irritate unless exposure is prolonged. Liquid will burn eyes and skin. (USCG, 1999)
Exposure treatment: Inhalation: if ill effects occur, remove person to fresh air, and get medical help. Ingestion: if swallowed and patient is conscious and not convulsing, promptly give milk or water, then induce vomiting; get medical help. No specific antidote known. Eye and skin: immediately flush with plenty of water for at least 15 min. For eyes, get medical help promptly. Remove, and wash contaminated clothing before reuse.
To fight fire use alcohol foam, carbon dioxide, /or/ dry chemical.
This compound is combustible. (NTP, 1992)
Use water spray, powder, alcohol-resistant foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.
Personal protection: filter respirator for organic gases and particulates adapted to the airborne concentration of the substance. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Wash away remainder with plenty of water.
Personal protection: filter respirator for organic gases and particulates adapted to the airborne concentration of the substance. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Wash away remainder with plenty of water.
Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Wash away remainder with plenty of water (extra personal protection: A/P2 filter respirator for organic vapour and harmful dust).
NO open flames. Closed system, dust explosion-proof electrical equipment and lighting. Prevent deposition of dust. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Separated from strong oxidants and strong acids. Dry. Keep in the dark. Well closed.Separated from strong oxidants, strong acids. Dry. Keep in the dark. Well closed.
no data available
no data available
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear safety goggles or eye protection in combination with breathing protection if powder.
Protective gloves.
Use local exhaust or breathing protection.
no data available
Solid. Waxy.
White.
no data available
44.5 - 45.5 °C.
248.8 - 254.5 °C. Atm. press.:1 013 hPa.
Combustible.
no data available
-1°C(lit.)
310 °C. Atm. press.:1 013 hPa.
no data available
pH of 5% aqueous solution = 11.5
1.98 cP at 45 deg C
Soluble (>=10 mg/ml) (NTP, 1992)
log Pow = -0.878. Temperature:25 °C.
0.002 hPa. Temperature:-5 °C.;0.08 hPa. Temperature:45 °C.
0.99 g/cm3. Temperature:20 °C.
4.59 (NTP, 1992) (Relative to Air)
no data available
Decomposes on heating and on burning. This produces toxic gases of nitrogen oxides. The solution in water is a medium strong base. Reacts with strong acids. Reacts violently with strong oxidants. This generates fire and explosion hazard.
no data available
Combustible when exposed to heat or flame...Dust explosion possible if in powder or granular form, mixed with air.DIISOPROPANOLAMINE is an aminoalcohol. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides. This compound may be sensitive to light and air. This compound will react with oxidizing materials. (NTP, 1992)
no data available
Can react with oxidizing materials.
The substance decomposes on heating and on burning producing toxic gases (nitrogen oxides).
no data available
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The substance is corrosive to the eyes, skin and respiratory tract. Inhalation of the aerosol may cause lung oedema. See Notes. The effects may be delayed. Medical observation is indicated.
no data available
No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20°C.
Diisopropanolamine achieved 39% of its theoretical oxygen demand using a sewage sludge following a 20 day incubation period(1). No biodegradation was observed at day 5 or day 10, suggesting that an acclimation period was required(1). Diisopropanolamine was classified as recalcitrant based on the results of screening studies using acclimated sewage sludge enrichment cultures(2).
An estimated BCF of 3 was calculated for diisopropanolamine(SRC), using a log Kow of -0.82(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC).
Batch equilibrium studies designed to evaluate the adsorption characteristics of diisopropanolamine in subsurface soils were conducted using aquifer material from three natural gas sites in Canada as well as montmorillonite and kaolinite clay materials(1). The adsorption isotherms were non-linear with Freundlich adsorption (Kf) coefficients ranging from 3.5 to 170, with the greatest values observed in the montmorillonite clay materials(1). Since diisopropanolamine has a pKa value of 9.1(1,2) it exists primarily as a cation in solution and a strong correlation between adsorption and the cation exchange capacity (CEC) of the material tested was observed(1). It was also noted that adsorption decreased with increasing solution electrolyte concentration as this resulted in competition for cation exchange sites in the clays and soils(1). Adsorption also decreased with increasing pH since at higher pH, a smaller percentage of diisopropanolamine exists in the protonated form.
no data available
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: No
IMDG: No
IATA: No
no data available
no data available
The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort.Rest and medical observation are therefore essential.Immediate administration of an appropriate spray, by a doctor or a person authorized by him/her, should be considered.