Skin corrosion, Sub-category 1A
Hazardous to the aquatic environment, short-term (Acute) - Category Acute 1
H314 Causes severe skin burns and eye damage
H400 Very toxic to aquatic life
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash ... thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P273 Avoid release to the environment.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P363 Wash contaminated clothing before reuse.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P316 Get emergency medical help immediately.
P321 Specific treatment (see ... on this label).
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P391 Collect spillage.
P405 Store locked up.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
no data available
Fresh air, rest. Half-upright position. Refer for medical attention.
Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Rinse mouth. Do NOT induce vomiting. Refer for medical attention .
Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]: TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. (ERG, 2016)
Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR as necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. Organic acids and related compounds
This chemical is a combustible liquid, but does not readily ignite. Poisonous gases include phosgene, hydrogen chloride, carbon monoxide are produced in fire. Use dry chemical, carbon dioxide, or alcohol or foam extinguishers. Vapors may travel long distances to ignition sources and flashback. Vapors in confined area may explode in fire. Storage containers and parts of containers may rocket great distances, in many directions. If materials or contaminated runoff enters waterways, notify downstream users of potentially contaminated waters. Notify local health and fire officials and pollution control agencies. From a secure, explosion-proof location, use water spray to cool exposed containers. If cooling streams are ineffective (venting sound increases in volume and pitch, tank discolors, or shows any signs of deforming), withdraw immediately to a secure position. If employees are expected to fight fires, they must be trained and equipped.
Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]: Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form. (ERG, 2016)
In case of fire in the surroundings, use appropriate extinguishing media.
Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Cautiously neutralize remainder. Then wash away with plenty of water.
Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Cautiously neutralize remainder. Then wash away with plenty of water.
Evacuate and restrict persons not wearing protective equipment from area of spill or leak until cleanup is complete. Remove all ignition sources. Ventilate area of spill or leak. Absorb liquids in vermiculite, dry sand, earth, or a similar non-organic materials and deposit in sealed containers. Keep this chemical out of a confined space, such as a sewer, because of the possibility of an explosion, unless the sewer is designed to prevent the build-up of explosive concentrations. It may be necessary to contain and dispose of this chemical as a hazardous waste. If material or contaminated runoff enters waterways, notify downstream users of potentially contaminated waters. Contact your Department of Environmental Protection or your regional office of the federal EPA for specific recommendations. If employees are required to clean-up spills, they must be properly trained and equipped.
Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Separated from metals, combustible substances, reducing agents, strong oxidants, strong bases and food and feedstuffs. Well closed. Ventilation along the floor.Prior to working with dichloroacetic acid you should be trained on its proper handling and storage. Store in tightly closed containers in a cool, well-ventilated area away from incompatible materials listed above. Metal containers involving the transfer of this chemical should be grounded and bonded. Where possible, automatically pump liquid from drums or other storage containers to process containers. Drums must be equipped with self-closing valves, pressure vacuum bungs, and flame arresters. Use only non-sparking tools and equipment, especially when opening and closing containers of this chemical. Sources of ignition such as smoking and open flames are prohibited where ethylene oxides is handled, used, or stored in a manner that could create a potential fire or explosion hazard. Wherever this chemical is used, handled, manufactured, or stored, use explosion-proof electrical equipment and fitting.
TLV: 0.5 ppm as TWA; (skin); A3 (confirmed animal carcinogen with unknown relevance to humans).MAK: 1.1 mg/m3, 0.2 ppm; peak limitation category: I(1); carcinogen category: 4
no data available
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear face shield or eye protection in combination with breathing protection.
Protective gloves. Protective clothing.
Use ventilation, local exhaust or breathing protection.
no data available
Dichloroacetic acid is a colorless crystalline solid melting at 49°F. Corrosive to metals and tissue.
Colorless liquid
Pungent odor
183°C(dec.)(lit.)
193°C(lit.)
Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.
no data available
170°C(lit.)
no data available
no data available
no data available
no data available
greater than or equal to 100 mg/mL at 59° F (NTP, 1992)
0.92
0.19 mm Hg ( 20 °C)
1.335g/mLat 20°C
4.5 (vs air)
no data available
Decomposes on heating. This produces toxic and corrosive fumes including hydrogen chloride. The substance is a strong acid. It reacts violently with bases and is corrosive. Attacks many metals. This produces flammable/explosive gas (hydrogen - see ICSC 0001).
no data available
DICHLOROACETIC ACID is probably hygroscopic. This chemical reacts with water or steam. It is incompatible with strong oxidizing agents, strong bases and strong reducing agents. (NTP, 1992)
no data available
DCA is a medium strong acid; incompatible with non-oxidizing mineral acids, organic acids, bases, acrylates, aldehydes, alcohols, alkylene oxides, ammonia, aliphatic, amines, alkanolamines, aromatic amines, amides, glycols, isocyanates, ketones. Attacks metals generating flammable hydrogen gas. Attacks some plastics, rubber and coatings.
When heated to decomposition it emits toxic vapors of /nitrogen oxides/ and hydrogen chloride.
no data available
no data available
no data available
no data available
There is inadequate evidence in humans for the carcinogenicity of dichloroacetic acid. There is sufficient evidence in experimental animals for the carcinogenicity of dichloroacetic acid. Overall evaluation: Dichloroacetic acid is possibly carcinogenic to humans (Group 2B).
no data available
Corrosive. The substance is corrosive to the eyes, skin and respiratory tract. Corrosive on ingestion. Inhalation of the vapour may cause lung oedema. See Notes. Exposure could cause death. Medical observation is indicated.
no data available
No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20°C.
AEROBIC: The biodegradability of dichloroacetic acid, at 10 ppm, was measured in both river water and seawater using the cultivation method; 14 and 8% degradation was reported for river water and seawater, respectively, after 3 days incubation(1). Based on these results, this compound was determined to be difficult to degrade(1). 0, 27, and 68% of the theoretical BOD in a BOD test was reached in 2, 5, and 10 days, respectively, following inoculation with sewage(2). Dichloroacetic acid was not biodegraded during a 5 day BOD test using a sewage inoculum(3). Dichloroacetic acid at 20 mg/L was >95% degraded in a 20 day BOD test; in a second screening test, this compound was 83% degraded after 30 days(4). Dichloroacetic acid, present at 100 mg/L, reached 97% of its theoretical BOD in 2 weeks using an activated sludge inoculum at 30 mg/L in the Japanese MITI test(5). Pure culture experiments show that aerobic degradation occurs via dehalogenation(6).
An estimated BCF of 3.2 was calculated for dichloroacetic acid(SRC), using a log Kow of 0.92(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC).
The Koc of dichloroacetic acid is estimated as 75(SRC), using a log Kow of 0.92(1) and a regression-derived equation(2). According to a classification scheme(3), this estimated Koc value suggests that dichloroacetic acid is expected to have high mobility in soil. The pKa of dichloroacetic acid is 1.26(4), indicating that this compound will primarily exist in the anion form in the environment and anions generally do not adsorb more strongly to soils containing organic carbon and clay than their neutral counterparts(5).
no data available
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: UN1764 (For reference only, please check.)
IMDG: UN1764 (For reference only, please check.)
IATA: UN1764 (For reference only, please check.)
ADR/RID: DICHLOROACETIC ACID (For reference only, please check.)
IMDG: DICHLOROACETIC ACID (For reference only, please check.)
IATA: DICHLOROACETIC ACID (For reference only, please check.)
ADR/RID: 8 (For reference only, please check.)
IMDG: 8 (For reference only, please check.)
IATA: 8 (For reference only, please check.)
ADR/RID: II (For reference only, please check.)
IMDG: II (For reference only, please check.)
IATA: II (For reference only, please check.)
ADR/RID: Yes
IMDG: Yes
IATA: Yes
no data available
no data available
The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort.Rest and medical observation are therefore essential.Immediate administration of an appropriate inhalation therapy by a doctor or a person authorized by him/her, should be considered.NEVER pour water into this substance; when dissolving or diluting always add it slowly to the water.