Acute toxicity - Category 4, Oral
Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 3
H302 Harmful if swallowed
H412 Harmful to aquatic life with long lasting effects
P264 Wash ... thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
P301+P317 IF SWALLOWED: Get medical help.
P330 Rinse mouth.
none
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
no data available
Fresh air, rest.
Rinse and then wash skin with water and soap.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Refer for medical attention .
no data available
Diphenamid ... is well absorbed & readily metabolized in mammals.
Use water spray, powder, alcohol-resistant foam, carbon dioxide.
Combustible. Gives off irritating or toxic fumes (or gases) in a fire.
Use water spray, powder, alcohol-resistant foam, carbon dioxide.
Do NOT let this chemical enter the environment. Then store and dispose of according to local regulations. If appropriate, moisten first to prevent dusting.
Do NOT let this chemical enter the environment. Then store and dispose of according to local regulations. If appropriate, moisten first to prevent dusting.
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
NO open flames. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Separated from strong acids, bases and strong oxidants.
no data available
no data available
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear safety spectacles.
Wear fire/flame resistant and impervious clothing. Handle with gloves. Gloves must be inspected prior to use. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Use local exhaust.
no data available
Diphenamid is a colorless to off-white crystals. Used as an herbicide.
WHITE
NO APPRECIABLE ODOR
132-136°C
382.4°C
Combustible. Gives off irritating or toxic fumes (or gases) in a fire.
no data available
173.3°C
no data available
no data available
no data available
no data available
SOLUBILITY (G/100 ML SOLVENT @ 27 DEG C): 18.9 IN ACETONE, 16.5 IN N,N-DIMETHYLFORMAMIDE, 32.0 IN PHENYL CELLOSOLVE, 0.026 IN WATER, 5.01 IN XYLENE
Log P: 2.17
3.00X10-8 mm Hg @ 25 deg C
1.07 g/cm3
no data available
no data available
Decomposes on heating at 210°C and on burning. This produces toxic and corrosive gases including nitrogen oxides. Reacts with bases, strong acids and strong oxidants.
Shelf life of the 80 w formulation is more than 2 yr
NonflammableDIPHENAMID is an amide. Amides/imides react with azo and diazo compounds to generate toxic gases. Flammable gases are formed by the reaction of organic amides/imides with strong reducing agents. Amides are very weak bases (weaker than water). Imides are less basic yet and in fact react with strong bases to form salts. That is, they can react as acids. Mixing amides with dehydrating agents such as P2O5 or SOCl2 generates the corresponding nitrile. The combustion of these compounds generates mixed oxides of nitrogen (NOx). This compound is decomposed by strong base or acid.
no data available
Incompatible with highly alkaline materials.
When heated to decomposition it emits toxic fumes of oxides of nitrogen.
no data available
no data available
no data available
no data available
no data available
no data available
no data available
no data available
Evaporation at 20°C is negligible; a nuisance-causing concentration of airborne particles can, however, be reached quickly.
Microorganisms appear to play a significant role in degradation of diphenamid in soil. certain species of soil fungi are capable of metabolizing diphenamid in vitro.
The bioconcentration factor (BCF) for diphenamid in aquatic organisms has been estimated to be 27(1). The low BCF value indicates that diphenamid would not be expected to bioconcentrate in aquatic organisms(1,SRC).
Diphenamid is not tightly adsorbed on soil colloids. it leaches rapidly in sandysoils but slowly in loam or clay soils. in sandy soils, retention of an effective concn in the weed seed germination zone with heavy rainfall can be a problem.
no data available
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: No
IMDG: No
IATA: No
no data available
no data available
Carrier solvents used in commercial formulations may change physical and toxicological properties.