Acute toxicity - Category 4, Oral
Specific target organ toxicity – repeated exposure, Category 1
Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 2
H302 Harmful if swallowed
H372 Causes damage to organs through prolonged or repeated exposure
H411 Toxic to aquatic life with long lasting effects
P264 Wash ... thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P301+P317 IF SWALLOWED: Get medical help.
P330 Rinse mouth.
P319 Get medical help if you feel unwell.
P391 Collect spillage.
none
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
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Move the victim into fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration and consult a doctor immediately. Do not use mouth to mouth resuscitation if the victim ingested or inhaled the chemical.
Take off contaminated clothing immediately. Wash off with soap and plenty of water. Consult a doctor.
Rinse with pure water for at least 15 minutes. Consult a doctor.
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
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VETERINARY: Injured capillaries cannot be mended, but other measures may save the animal. Restraint & handling should be minimized. A sedative or tranquilizer may be of assistance in restraint, calming ... & reducing locomotion, thus decr tissue oxygen demand. Oxygen may be given, but manual pumping of chest is not advisable. Dyspnea may be relieved by thoracentesis. Clotting factors should be provided in form of blood transfusion (20 ml/kg, 1/2 injected quickly). Warfarin should be antagonized with slow iv injection of vitamin K1. Dogs & cats are given 5 mg/kg. This dose is repeated for 2 more days, using im route. Larger animals are given 0.5 to 1 mg/kg, & oral vitamin K1 should be admin daily for 4-6 days. The vitamin will not evoke a sudden dramatic cure; but bleeding tendency will gradually abate as clotting factors begin to be synthesized ... Menadione (vitamin K3) is not as effective as vitamin K1 ... Residual defects such as lameness or CNS signs from localized hemorrhages may disappear with gradual resorption of extravasated blood. Liver damage may be compensated by regeneration of hepatic cells. Warfarin
Use dry chemical, carbon dioxide or alcohol-resistant foam.
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Wear self-contained breathing apparatus for firefighting if necessary.
Avoid dust formation. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. Use personal protective equipment.Wear chemical impermeable gloves. Ensure adequate ventilation.Remove all sources of ignition. Evacuate personnel to safe areas.Keep people away from and upwind of spill/leak.
Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Dicumarol should be stored in well-closed containers at a temperature below 40 degrees C (104 deg F), preferably 15 to 30 deg C (59 to 86 deg F), and kept away from direct sunlight. The manufacturer recommends storage below 25 deg C (77 deg F).
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Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear tightly fitting safety goggles with side-shields conforming to EN 166(EU) or NIOSH (US).
Wear fire/flame resistant and impervious clothing. Handle with gloves. Gloves must be inspected prior to use. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
If the exposure limits are exceeded, irritation or other symptoms are experienced, use a full-face respirator.
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Solid
White or creamy white, crystalline powder
Slight, pleasant odor
290-292°C(lit.)
620.702°C at 760 mmHg
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1.573g/cm3
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When heated to decomposition it emits acrid smoke and fumes.
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An estimated BCF of 8 was calculated for dicumarol(SRC), using a log Kow of 2.07(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC), provided the compound is not altered physically or chemically after released into the environment(SRP).
The Koc of dicumarol is estimated as 320(SRC), using a log Kow of 2.07(1) and a regression-derived equation(2). According to a classification scheme(3), this estimated Koc value suggests that dicumarol is expected to have moderate mobility in soil.
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The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
ADR/RID: Yes
IMDG: Yes
IATA: Yes
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